KEVINK0000
Thread starter
And another with varying states of tune over its lifespan:
Yes, this generation of QS was always SP. Its the SP, GF6A stuff.What immediately stands out is Calcium and Boron. Boron on this VOA is at 108. On your three UOA's it's ~30, all of them. Calcium is >1,400 on this VOA, while yours are all ~1,300ppm. Not huge differences but enough to raise an eyebrow.
Was the version you used SP?
Yes, and there was one that got Euro delivery and the factory fill was clearly a 20w. I will try to find it. This engine is now spec'd by BMW for 0W-20, FWIW.So far, all of the ones you shared have higher viscosity than yours. Most have fuel.
Not surprising, there have been plenty of engines back-spec'd in the pursuit of improving fuel economy. Ford was doing that around 2000, back spec'ing to 5W-20. But BMW does have their own approval process for the 0W-20, on top of the ACEA approvals, and the oxidation test is part of that. These oils also still have higher levels of AW additives. Mobil's ESP X2 0W-20 for example, which is ACEA C6, Porsche C20...etc has 880ppm of phosphorous/950ppm zinc while their SP/GF-6A 0W-20 has 760/830.Yes, and there was one that got Euro delivery and the factory fill was clearly a 20w. I will try to find it. This engine is now spec'd by BMW for 0W-20, FWIW.
Interesting, because clearly, boron stands out here as being different from this VOA (as does Calcium, but less so in terms of magnitude).Yes, this generation of QS was always SP. Its the SP, GF6A stuff.
Boron appears to be an additive that depletes with use. I've noticed it on several UOAs where I've also got a VOA. Starts high, and the more use the oil has, the lower it gets on the UOA.Boron on this VOA is at 108. On your three UOA's it's ~30, all of them.
I have a bunch of UOA and VOA data with B.....will have a look today and see if your observation holds true with my data.Boron appears to be an additive that depletes with use. I've noticed it on several UOAs where I've also got a VOA. Starts high, and the more use the oil has, the lower it gets on the UOA.
edit: https://bobistheoilguy.com/forums/t...mi-2014-mazda-3-with-2-0l.352414/post-6056224
https://bobistheoilguy.com/forums/threads/boron-depletion.330713/I have a bunch of UOA and VOA data with B.....will have a look today and see if your observation holds true with my data.
Yes, emissions spectrography can sometimes be used to detect certain impending failures but not always. However, I thought this whole post (and the previous one) was that a UOA can be used to show that an ILSAC oil is "as good" as one with BMW Longlife approval? Did that change? You've got two topics going here.This one the owner "caught" the timing chain problem before failure. I think there was actually more going on there, but here is another report:
He's derailing his topic on purpose as he still hasn't answered at least the one question as to why he is doing this.Yes, emissions spectrography can sometimes be used to detect certain impending failures but not always. However, I thought this whole post (and the previous one) was that a UOA can be used to show that an ILSAC oil is "as good" as one with BMW Longlife approval? Did that change? You've got two topics going here.
Nope.He's derailing his topic on purpose as he still hasn't answered at least the one question as to why he is doing this.
If you look back on that thread, the oil report did not show anything amiss. The owner spotted shiny particles in the drain contents. I see shiny particles in every drain I do, regardless of vehicle. BMW said it was plastic (yes plastic) from the guides. The guides at this point would have been anything but shiny. They gave him a partially paid goodwill update out of warranty. I believe it was used as an excuse (by the BMW dealer) for BMW to get into his engine and fix the known problem with the guides, and extend some goodwill to the owner, since the warranty had expired very soon before the service was done. The point was the repair was done before anything was noted on the UOA. Which actually goes to the point you tend to make, pretty much everywhere.Yes, emissions spectrography can sometimes be used to detect certain impending failures but not always. However, I thought this whole post (and the previous one) was that a UOA can be used to show that an ILSAC oil is "as good" as one with BMW Longlife approval? Did that change? You've got two topics going here.
Yes, good point. However, if we look at the rate of depletion, it appears to be twice as high compared to Artem's if this is all just due to that.Boron appears to be an additive that depletes with use. I've noticed it on several UOAs where I've also got a VOA. Starts high, and the more use the oil has, the lower it gets on the UOA.
edit: https://bobistheoilguy.com/forums/t...mi-2014-mazda-3-with-2-0l.352414/post-6056224
Either way, metallic particles in the oil do not show up on emission spectrography without some sort of sample modification. When I ran UOA in college for our fluid power department some rather catastrophic failures (particles in oil) would not affect the analysis unless an acid digestion was performed. ICP does not measure particles in a sample it measures elements in solution. This is why I noted that sometimes a UOA can be indicative of certain impending failures.If you look back on that thread, the oil report did not show anything amiss. The owner spotted shiny particles in the drain contents. I see shiny particles in every drain I do, regardless of vehicle. BMW said it was plastic (yes plastic) from the guides. The guides at this point would have been anything but shiny. They gave him a partially paid goodwill update out of warranty. I believe it was used as an excuse (by the BMW dealer) for BMW to get into his engine and fix the known problem with the guides, and extend some goodwill to the owner, since the warranty had expired very soon before the service was done. The point was the repair was done before anything was noted on the UOA. Which actually goes to the point you tend to make, pretty much everywhere.
I have a VOA and a couple of UOAs with ST FS HM 5W20 that I’ll dig up when I get a chance. They should be posted in the appropriate forums here if someone has time to look them up before this evening.Yes, good point. However, if we look at the rate of depletion, it appears to be twice as high compared to Artem's if this is all just due to that.
Kevin - 108 -> 34 in 5,200 miles = 14.2ppm/1,000 miles
Artem - 61 -> 35 in 3,739 miles = 6.9ppm/1,000 miles
Which then brings us to @kschachn's point about if this is depletion, where is it going?
According to that article it is reacting with water and precipitating out as an insoluble at the bottom of the pan, assuming this is the same mechanism for this particular boron compound. Elements don't "go" anywhere of course, they have to be there somewhere or else shot out of the tailpipe.Which then brings us to @kschachn's point about if this is depletion, where is it going?