quote:
Originally posted by A4NCAR:
- Ecessive carbon build up from non-synthetic oil?
- Is it caused by heat?
- Oil screen?
- Turbo?
The requirements for sludge are heat, particulate contaminants, and moisture.
What happens is that particles of dirt (which may be products of the decomposition of the oil itself), sulfur, and blowby are bound together with moisture.
The conditions for the formation of these sludge precursors include certain oxides in the blowby - characteristic of lean burn engines, low volatility fuel, improper venting of the crankcase, low temperature operating conditions, low crankcase capacity, and long drain intervals, all of which increase the amount of sludge precursors and binders in the motor oil.
They then undergo chemical reactions which may involve decomposition, the formation of acids, and ultimately polymerization.
These reactions are promoted by higher temperatures when the precursor-bearing oil comes in contact with the pistons and cylinder walls and with modern high temperature cylinder head designs. The precursors adhere to particulates, they begin to aggregate, and then polymerize.
Sludge can be prevented by filtration, avoidance of low operating temperatures, proper maintenance of the crankcase ventilation, frequent oil changes, and the use of motor oils with additives and blend stocks that disperse sludge binders.
One of the things noted in the early days of synthetic motor oils was the absence of sludge formation. It turned out that the breakdown of the mineral oil itself was a contributor to sludge, something that improved base stocks and additives has greatly alleviated.
I can envision an automobile operated with a marginal mineral oil in primarily short-trip driving with extended oil change intervals becoming a sludge precursor generator, which coupled with new cylinder head designs results in the precursor-laden oil being subjected to high temperature and pressure as it lubricates the cylinders and overhead camshaft.
This seems to be the scenario at Toyota and VW, where sludge problems followed design changes that raised cylinder head temperatures and recommendations for extended motor oil drain intervals.