Can thicker oil prevent rocker arm failures in Pentastar 3.6 V6?

it’s actually pretty hard to tell if an oil is shearing
That's true. I would say that Red Line shears less than others. Red Line Oils, especially those that don't have a 0W winter rating, tend to thicken with heat and stay that way through the OCI. It would be awesome if the HTHS was measured at the end of the OCI.
 
Even the best VII that do not permanently shear will have a expansion limit. And VII will have a temporary lower viscosity affect at MOFT. It is best to use base oil with a high VI.
The highest VI base oils are PAO typically. You can count on one hand how many major blenders use PAO in their products.

You can get an idea as to how much VII is in the finished product by the VI. If the oil has a relatively low VI and is also using PAO, you know that it has very little VII. A good example is Ravenol ECS 0w-20:
Screen Shot 2022-05-26 at 3.40.16 PM.webp


Which has a lower VI than many 5w-20's. We are still debating the accuracy of M1 EP 0w-20's VI, but if it is accurate, that's an oil that's basically a monograde.
 
Red Line Oils, especially those that don't have a 0W winter rating, tend to thicken with heat and stay that way through the OCI. It would be awesome if the HTHS was measured at the end of the OCI.
Only way an oil could thicken with heat (barring any other operational factors) is if the Noack was high and the light molecules vaporized out of the oil. Red Line oils seem to have pretty low Noack vavues
 
Which one of those specs show that it won't exhibit any permanent shear?
Shear happens with VII… VII will make pour point higher temp. and HTHS numbers lower and Noack shows the base oil quality. They all say very low VII. IMO…
 
Shear happens with VII… VII will make pour point higher temp. and HTHS numbers lower and Noack shows the base oil quality. They all say very low VII.
Yes, shear happens with VIIs ... so if it has any VIIs then it will still eventually experience permanent shear. The claim (not by you) was there was "no shear", meaning no permanent loss of viscosity due to shearing. HTHS won't necessarily become lower from VIIs. HTHS viscosity has a lot to do with the base oil's HTHS to start with.

HTHS viscosity at 150C and 1M/sec shear rate is what the dynamic viscosity is under those conditions. Two oils can have the same exact HTHS viscosity and be totally different formulations. When shear rates exceed 1M/sec is when the difference in base oil and VIIs can show differences in HTHS viscosity between two oils that have the same HTHS at 150C and 1M/sec shear rate.
 
Only way an oil could thicken with heat (barring any other operational factors) is if the Noack was high and the light molecules vaporized out of the oil. Red Line oils seem to have pretty low Noack vavues
Oxidation.

AMSOIL's lubes used to do this too when run on longer OCI's, showing oxidative thickening.
 
Oxidation.

AMSOIL's lubes used to do this too when run on longer OCI's, showing oxidative thickening.
Yes ... but isn't oxidation also occurring while an oil is being tested for Noack? Or is the oxidation more of a long term "operational factor" as I mentioned. Oils that oxidize are also more prone to degradation and sludging ... so do RedLine oils (or any others that actually thicken during use) have more likelihood of sludging compared to others if all ran the same OCI?
 
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Oxidation.

AMSOIL's lubes used to do this too when run on longer OCI's, showing oxidative thickening.
I think they're still doing it, to some degree. I wouldn't run AMSOIL any longer in an engine than Mobil 1. Let me back up for a second: given their expertise, I trust Mobil 1 more than I trust AMSOIL, period.
 
Yes ... but isn't oxidation also occurring while an oil is being tested for Noack? Or is the oxidation more of an "operational factor" as I mentioned. Oils that oxidize are also more prone to sludging ... do RedLine oils (or any others that actually thicken during use) have more likelihood of sludging compared to others if all ran the same OCI?
Oxidation is more of an operation factor (and normal for all base oils during service) and is often countered or overwhelmed by permanent shear and fuel dilution. Cheap base oils may oxidize and break-down quicker, but I don't think there's any evidence of oils we've seen oxidatively thicken in service (AMSOIL, Redline) produce sludge (which requires moisture) or varnish in the process, which is a more complex process involving breakdown and plating-out of deposits that can no longer be held in suspension.
SludgeVarnish.JPG


If you start with base oils with naturally higher VI and are using less VII, there's less shearing possible, so ultimately oxidative thickening can become the primary driver of viscosity change. While PAO is more resistant to thickening, it is not immune:

Screen Shot 2022-05-26 at 5.16.58 PM.png
 
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In Red Line's case, it has more to do with their choice and quantity of esters used in their formulations.
I'd think it would be the PAO that would do it, as POE is more resistant to high temp oxidation (which is why it is used for turbine oils) and PAO makes up the bulk of their base oil blend, unless you've read something on the subject that I haven't?
 
Where does AN follow in this super base oil discussion?
Group V - high heat resistance, poor cold flow compared to PAO, no competition with the additives, unlike esters.

I'd think it would be the PAO that would do it, as POE is more resistant to high temp oxidation (which is why it is used for turbine oils) and PAO makes up the bulk of their base oil blend, unless you've read something on the subject that I haven't?
I'm sorry, I can't say I have. It was just my assumption based on UOAs I've seen and some of our discussions.

It always seemed that they used more POE in their 5W-X and 10W-X motor oils. This was more evident before they closed their MSDS files completely to prying eyes, replacing the base oil composition with the blanket statement of "90% Synthetic..."

Their gear oils seem to be formulated the same way, with 75W-85 having the most PAO (~60% PAO). As you move up to 75W-90, it's 50%, then 75W-140 is 30%~40% PAO IIRC.

Now I wonder if I should either question the quality of their PAO, how they use POE and other esters, or how they formulate their oils? One thing is for sure: I've seen RL 5W-30 increase in viscosity much more than RL 0W-20 and RL 0W-30 over an OCI. I talked to Red Line about this, and while they said that their 0W motor oils should at least stay in grade, the behavior of 5W-X lubes increasing in viscosity over an OCI is expected and desirable.
 
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Where does AN follow in this super base oil discussion?


As @Rod Knock noted, AN's have complimentary properties to PAO and, unlike POE, doesn't impose surface competition for additives. So, you can dial back the esters (typically POE) to provide sufficient seal swell to counteract PAO's harshness, then use AN's for solubility, which results in a better performing product.
 
The video says AN has comparable POE affect with seal swell. I kinda wonder why they have all three base oils in a few Mobil 1 oils?
 
Group V - high heat resistance, poor cold flow compared to PAO, no competition with the additives, unlike esters.


I'm sorry, I can't say I have. It was just my assumption based on UOAs I've seen and some of our discussions.

It always seemed that they used more POE in their 5W-X and 10W-X motor oils. This was more evident before they closed their MSDS files completely to prying eyes, replacing the base oil composition with the blanket statement of "90% Synthetic..."

Their gear oils seem to be formulated the same way, with 75W-85 having the most PAO (~60% PAO). As you move up to 75W-90, it's 50%, then 75W-140 is 30%~40% PAO IIRC.

Now I wonder if I should either question the quality of their PAO, how they use POE and other esters, or how they formulate their oils? One thing is for sure: I've seen RL 5W-30 increase in viscosity much more than RL 0W-20 and RL 0W-30 over an OCI. I talked to Red Line about this, and while they said that their 0W motor oils should at least stay in grade, the behavior of 5W-X lubes increasing in viscosity over an OCI is expected and desirable.
K, I expect what we are seeing are the result of the use of heavier PAO bases, minimal use of VII and very shear stable VII. This means that any viscosity loss from shear is going to be minimal, so then the only real driver of viscosity loss is fuel dilution. If you don't have an abundance of that, then, in service, as the base oils oxidize (mostly the PAO) even though it is slight, compared to other, less expensive bases, it ultimately ends up driving up viscosity.

In cheaper blended oils this tendency is masked or even overridden by viscosity loss due to shear.

Of course we see more and more fuel dilution with DI engines, which may be why we see less thickening nowadays :)

The last SDS I have for Redline white bottle was for their 5w-30, and it showed majority PAO (and remember, you still need DI package and VII):
1653608518898.png


*Removed wrong screencap, thanks @Rod Knock lol
 
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