You would have to look at the spec sheet for each oil and compare the CCS and MRV viscosity numbers. A 0W will have less CCS and MRV viscosity vs a 5W, and a 5W will have less CCS and MRV viscosity than a 10W.
But if you really want to split hairs you start comparing the CCS and MRV numbers between different oils of the same W rating - ie, just compare 0W oils to 0W oils and 5W oils to 5W oils. If you want the very best cranking and pumpability you would choose a 0W grade oil with the least CCS and MRV viscosity between them all. SAE J300 defines the max limits for each W grade - latest version shown below. Of course there are other aspects of motor oils that should be looked at besides just the W rating ... but what I said above would just be focusing on the W rating aspect.
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