Originally Posted By: kschachn
Ahh yes. The highly regarded Heated Spoon Test for Additive Loss. How could I have missed that.
Probably your oil rings are not that picky. Believe or not, but they don't care about your believes. They just got covered by almost diamond hard deposits from oil additives and that's it.
Again, I disassembled at least 6-7 different engines. And I have never, never seen a scientist inside a cylinder
So simplest test sometimes give you an idea what is good or wrong, no rocket science is required.
Originally Posted By: SteveSRT8
^^^^HAW! What a laugh.
The infamous burnt spoon test! The new standard in oil evaluation!
And he dissed Toyota's 0W-20, too.
Seriously, almost any branded synthetic in the spec'd weight is probably better than needed...
You are right: less knowledge - better sleep.
Originally Posted By: BlackWidow
Originally Posted By: timeau
At least europenian Shell Ultra is awful.
Why?
I am glad that you asked that. Sorry for a long explanation, but this is necessary to explain this.
First of all: why synthetic oils are used?
1. They are more expensive and bring more money for manufactures;
2. They can be used in very cold climate;
3. They provide longer OCI.
Item number 2 is not important unless you live in Alaska. So, please, pay attention on item 1 and 3. Actually, number 1 is the most significant, and number 3 provides an excellent explanation of overpaying. Mighty advertisement makes people think that synthetic oil bring them something magic that they have never had before. Same as Starbucks, Coca-Cola, etc., where people are paying by their health. In case of synthetic oil people pay by their engines.
You definitely know about the chemical polarity. In plain language and quite roughly this is an ability to dissolve other substances. Mineral oils have high polarity: they dissolve additives completely. Heating can't make additives to precipitate. That's what you can see on a picture above, left bottle.
PAO or Group III oils are low polar liquids, they just can't dissolve additives. Manufactures need to do additional investigations to solve this problem. How do you think why Royal Purple has Group II in it? This is extremely illogical: they advertise and sell Group IV oils, right? So the answer is: mineral component is used to dissolve additives.
Another example. You probably read about some suspension on the bottom of oil bottle. People wonders what is this. These are precipitated additives that came from long storing oils. And almost all of these oils are Group III.
So in some, but not all synthetic oil additives could precipitate. No science required to check this: just heat it. Or read about new fashion in oil industry.
Few citations from there:
Quote:
The hot gases in the turbocharger turbine area create a very harsh environment for the oil in the bearing housing. This is probably the most severe area in the whole engine for the oil, with oil temperatures exceeding 350 degrees C for short periods.
So 350C is not exotic temperature any more. Remember this number. Actually, piston rings on non-turbo cars could easily have 300C too.
Quote:
For example, a good combination of antioxidants and detergents can significantly reduce the formation of oxidized species that create sludge, and a balanced mixture of detergents can reduce deposit formation on the pistons. Finally, optimized dispersants can solubilize sludge, preventing its separation from the lubricant.[/qoute]
Industry & OEM Actions
Ahh yes. The highly regarded Heated Spoon Test for Additive Loss. How could I have missed that.
Probably your oil rings are not that picky. Believe or not, but they don't care about your believes. They just got covered by almost diamond hard deposits from oil additives and that's it.
Again, I disassembled at least 6-7 different engines. And I have never, never seen a scientist inside a cylinder
Originally Posted By: SteveSRT8
^^^^HAW! What a laugh.
The infamous burnt spoon test! The new standard in oil evaluation!
And he dissed Toyota's 0W-20, too.
Seriously, almost any branded synthetic in the spec'd weight is probably better than needed...
You are right: less knowledge - better sleep.
Originally Posted By: BlackWidow
Originally Posted By: timeau
At least europenian Shell Ultra is awful.
Why?
I am glad that you asked that. Sorry for a long explanation, but this is necessary to explain this.
First of all: why synthetic oils are used?
1. They are more expensive and bring more money for manufactures;
2. They can be used in very cold climate;
3. They provide longer OCI.
Item number 2 is not important unless you live in Alaska. So, please, pay attention on item 1 and 3. Actually, number 1 is the most significant, and number 3 provides an excellent explanation of overpaying. Mighty advertisement makes people think that synthetic oil bring them something magic that they have never had before. Same as Starbucks, Coca-Cola, etc., where people are paying by their health. In case of synthetic oil people pay by their engines.
You definitely know about the chemical polarity. In plain language and quite roughly this is an ability to dissolve other substances. Mineral oils have high polarity: they dissolve additives completely. Heating can't make additives to precipitate. That's what you can see on a picture above, left bottle.
PAO or Group III oils are low polar liquids, they just can't dissolve additives. Manufactures need to do additional investigations to solve this problem. How do you think why Royal Purple has Group II in it? This is extremely illogical: they advertise and sell Group IV oils, right? So the answer is: mineral component is used to dissolve additives.
Another example. You probably read about some suspension on the bottom of oil bottle. People wonders what is this. These are precipitated additives that came from long storing oils. And almost all of these oils are Group III.
So in some, but not all synthetic oil additives could precipitate. No science required to check this: just heat it. Or read about new fashion in oil industry.
Few citations from there:
Quote:
The hot gases in the turbocharger turbine area create a very harsh environment for the oil in the bearing housing. This is probably the most severe area in the whole engine for the oil, with oil temperatures exceeding 350 degrees C for short periods.
So 350C is not exotic temperature any more. Remember this number. Actually, piston rings on non-turbo cars could easily have 300C too.
Quote:
For example, a good combination of antioxidants and detergents can significantly reduce the formation of oxidized species that create sludge, and a balanced mixture of detergents can reduce deposit formation on the pistons. Finally, optimized dispersants can solubilize sludge, preventing its separation from the lubricant.[/qoute]
Industry & OEM Actions
Industry specifications for engine oils are generally slow to adopt the latest engine types in the list of required performance tests. However, industry organizations and individual OEMs are recognizing that tests based on older engines can no longer guarantee the protection needed for modern TGDI engines. An example can be found in the European ACEA Oil Sequences, where a sludge test using a TGDI engine is currently under development. Also, a TGDI oxidation/ deposit test has been proposed, with deposits in the turbo bearing area being a key parameter.
One more time: this is an article from http://gf-6.com. Is it quite reputable? I think so. Also it have a set of excellent graphs and photos.
Back to Shell Ultra.
Heating this oil in a laboratory to 380 C produces pretty poor result:
http://img-fotki.yandex.ru/get/6507/16219540.3/0_8c85b_c35c6789_orig
Additives precipitate on the bottom of the flask. Compare with Mobil1:
http://img-fotki.yandex.ru/get/6403/16219540.1/0_8a647_a56af106_XXL
and
http://img-fotki.yandex.ru/get/6403/16219540.1/0_8a645_78cbc5b6_XXL
Otherwise, Pennzoil advertise their Ultra as the oil for clean pistons. This makes me think that they would not dare to do that without any reason. So Pennzoil Ultra could be OK, I just don't have enough information.
P.S. Havoline Synthetic: what a mess...
http://img-fotki.yandex.ru/get/6503/16219540.1/0_8a63d_2d1f9310_XXL
Mazda OEM:
http://img-fotki.yandex.ru/get/6505/16219540.3/0_8c855_c3e7614d_orig