Originally Posted By: JHZR2
Re-read what I asked. Yes, sure, frequent switching kills them, but what is the component that dies???
Sorry, I misread your question.
Quote:
End of life
The end of life failure mode for fluorescent lamps varies depending on how they are used and their control gear type. Often the light will turn pink (see "Loss of mercury") with black burns on the ends of the lamp due to sputtering of emission mix (see below). The lamp may also flicker at a noticeable rate (see "Flicker problems"). More information about other normal tube failure modes including the above are as follows:
Emission mix
Closeup of the filament on a low pressure mercury gas discharge lamp showing white thermionic emission mix coating on the central portion of the coil acting as hot cathode. Typically made of a mixture of barium, strontium and calcium oxides, the coating is sputtered away through normal use, often eventually resulting in lamp failure.
The "emission mix" on the tube filaments/cathodes is necessary to enable electrons to pass into the gas via thermionic emission at the tube operating voltages used. The mix is slowly sputtered off by bombardment with electrons and mercury ions during operation, but
a larger amount is sputtered off each time the tube is started with cold cathodes. The method of starting the lamp has a significant impact on this. Lamps operated for typically less than 3 hours each switch-on will normally run out of the emission mix before other parts of the lamp fail. The sputtered emission mix forms the dark marks at the tube ends seen in old tubes. When all the emission mix is gone, the cathode cannot pass sufficient electrons into the gas fill to maintain the discharge at the designed tube operating voltage. Ideally, the control gear should shut down the tube when this happens. However, some control gear will provide sufficient increased voltage to continue operating the tube in cold cathode mode, which will cause overheating of the tube end and rapid disintegration of the electrodes (filament goes open-circuit) and filament support wires until they are completely gone or the glass cracks, wrecking the low pressure gas fill and stopping the gas discharge.
Ballast electronics
This may occur in compact fluorescent lamps with integral electrical ballasts or in linear lamps. Ballast electronics failure is a somewhat random process that follows the standard failure profile for any electronic device. There is an initial small peak of early failures, followed by a drop and steady increase over lamp life. Life of electronics is heavily dependent on operating temperature—it typically halves for each 10 °C temperature rise. The quoted average life of a lamp is usually at 25 °C ambient (this may vary by country). The average life of the electronics at this temperature is normally greater than this, so at this temperature, not many lamps will fail due to failure of the electronics. In some fittings, the ambient temperature could be well above this, in which case failure of the electronics may become the predominant failure mechanism. Similarly, running a compact fluorescent lamp base-up will result in hotter electronics, which can cause shorter average life (particularly with higher power rated ones). Electronic ballasts should be designed to shut down the tube when the emission mix runs out as described above. In the case of integral electronic ballasts, since they never have to work again, this is sometimes done by having them deliberately burn out some component to permanently cease operation.
In most CFLs the filaments are connected in series, with a small capacitor between them. The discharge, once lit, is in parallel to the capacitor and presents a lower-resistance path, effectively shorting the capacitor out. One of the most common failure modes of cheap lamps is caused by underrating this capacitor (using lower-voltage, lower-cost part), which is very stressed during operation, leading to its premature failure.[29]
Phosphor
The phosphor drops off in efficiency during use. By around 25,000 operating hours, it will typically be half the brightness of a new lamp (although some manufacturers claim much longer half-lives for their lamps). Lamps that do not suffer failures of the emission mix or integral ballast electronics will eventually develop this failure mode. They still work, but have become dim and inefficient. The process is slow, and often becomes obvious only when a new lamp is operating next to an old one.
Loss of mercury
As in all mercury-based gas-filled tubes, mercury is slowly absorbed into glass, phosphor, and tube electrodes throughout the lamp life, where it can no longer function. Newer lamps now have just enough mercury to last the expected life of the lamp. Loss of mercury will take over from failure of the phosphor in some lamps. The failure symptoms are similar, except loss of mercury initially causes an extended run-up time to full light output, and finally causes the lamp to glow a dim pink when the mercury runs out and the argon base gas takes over as the primary discharge.[30]
Subjecting the tube to asymmetric waveforms, where the total current flow through the tube does not cancel out and the tube effectively operates under a DC bias, causes asymmetric distribution of mercury ions along the tube due to cataphoresis. The localized depletion of mercury vapor pressure manifests as pink luminescence of the base gas in the vicinity of one of the electrodes, and the operating lifetime of the lamp may be dramatically shortened. This can be an issue with some poorly designed inverters.[31]
The same effect can be observed with new tubes. Mercury is present in the form of an amalgam and takes some time to be liberated in sufficient amount. New lamps may initially glow pink for several seconds after startup. This period is minimized after about 100 hours of operation.[32]
Burned filaments
The filaments can burn at the end of the lamp's lifetime, opening the circuit and losing the capability to heat up. Both filaments lose function as they are connected in series, with just a simple switch start circuit a broken filament will render the lamp completely useless. Filaments rarely burn or fail open circuit unless the filament becomes depleted of emitter and the control gear is able to supply a high enough voltage across the tube to operate it in cold cathode mode. Some digital electronic ballasts are capable of detecting broken filaments and can still strike an arc with one or both filaments broken providing there is still sufficient emitter. A broken filament in a lamp attached to a magnetic ballast often causes both lamps to burn out or flicker.
http://en.wikipedia.org/wiki/Fluorescent_lamp
