I would love to have 45 degree air all the time. If I'm stuck in traffic, the vents will get up to 55-56 degrees and the cabin temp gets above 80. Then again, it is very hot and humid where I live and it's better than nothingYour temps seem fine to me- a 50 degree differential while driving and slightly under that while stopped I would consider fantastic.
Exactly how cold do you want the car to be? Is 45 degrees coming from the vents not comfortable? Understand that when stopped, your AC performance will drop some, that's normal. I question the accuracy of the measuring instrument used by anyone reporting temps in the 30's when it's 90+ degrees out.
I think the issue might come down to expectations. Maybe time to tint some windows?
I would invest in some gauges and you will get a much better idea whether the system is performing normally.

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