Originally Posted By: burgessdg
Originally Posted By: ChrisD46
What differences do you believe you would see in the structure of the oil when comparing a 0W20 vs. a 0W30 oil after 7,500 miles ? Would there be a concern for the 30W sheering down to a 20W or more prone to additive loss due to larger delta from 0W to 30 vs. the 0W20 ?
Not an oil engineer but from what I have read the first # is the base oil. Then polymers are added that thicken the oil when hot, making that base oil act like a thicker oil when hot, that thickness is then the second #. Soooo, to answer your question, as the oil ages, additives go away and you end up with more 0 than 20. To the point where you could end up with just 0. Make sense?
No.
The first number is the cold performance target; it is the oil's performance (for the case of a 0W) in terms of MRV @ -40C and CCS (Cold Cranking Simulator) @ -35C. Each cold classification has a different set of temperatures associated with it. To obtain the 5W rating for example, your MRV must be below the limit (60,000cP) @ -35C and your CCS must be below the limit (in this case, 6,600cP) @ -30C.
This chart illustrates it well:
Oils are a blend of base oils, with varying levels of cold and hot performance. It is quite possible to blend a 5W-30 for example with no VII's whatsoever. Redline's 5w-30 is an example of that. It capitalizes on the naturally excellent characteristics of the base oil blend to obtain the 5W rating and is also a 30 weight @ 100C. Due to this fact it does not shear.
Now of course blending a VII-free multigrade is expensive. So typically they will use a base oil blend that ends up "somewhere in the middle" and will use VII's and PPD's to tweak the oil to get its viscosity characteristics to where they need to be. It is a delicate balancing act building a fully formulated motor oil that will meet the myriad of performance approvals some of them are required to obtain, many of which test temporary and permanent shear and other aspects of the lubricant that will degrade in use.
Now, as an aside, but it may interest you, the chart shows that there is a minimum 100C viscosity for the various xW ratings. They are not common anymore, but you used to be able to buy an oil that was simply 10W or 15W:
The 20W-20 that Shannow was mentioning, you'll notice it has the same minimum limits (5.6cP @ 100C) for hot performance for both the summer and winter ratings.
Solarent spoke on the blending process before about what viscosity bases he would use when making something like a 5w-40 and ultimately IIRC (but don't quote me on this), you ended up with a base oil blend that satisfied the requirements for 5W and fell somewhere in the 30 weight range when hot. The product was then manipulated with some VII's to bump it into the 40 weight territory. This is also, IMHO, why you see the 5W-40 HDEO's shear down into 30's in applications like the 6.0L PSD, where the injection system destroys the polymers.