100LL avgas suffers from the same problem as Sunoco Standard 110. In an NA automotive engine, at ground level, it can be sluggish in terms of throttle response. This is due to the initial boiling point and lower end of the distillation curve being rather high. Avgas has to have a higher boiling point to ensure the fuel doesn't evaporate at high altitude and cause vapor lock that stalls the engine mid-flight. They're not concerned about how the fuel performs at ground level. It's plenty adequate enough for planes that are rich at takeoff anyway. They care that the fuel is stable at 15,000 ft where air pressure is only about half that of sea level. It'll still run fine in a car engine at ground level, just throttle response will suffer some.
The distillation curve of 100LL is generally different than today's auto fuel. However, that does not mean it evaporates slowly or will result in sluggish throttle response. 100LL works incredibly well in certain engines.
Pilots have been throwing 100LL on the ground for ages. Before the ramp attendant can get out to the plane to yell at the pilot, it's evaporated and gone. leaving no visible evidence.
100LL will vaporize at sub zero temps, and engines will both start and run properly under more conditions than typical auto fuels. This is generally of no advantage for the typical race fuel user.
Before anyone purchases 'race' fuel it is best to have a good understanding of the fuel and its characteristics. There are no true 101+ octane 'non-oxygenated' unleaded fuels. In real world terms, 96 octane R+M/2 is about it for a standard unleaded fuel.
Many of Sunoco's high octane unleaded fuels are highly oxygenated. Generally with lots of ethanol.