Just to set the record straight:
- The ruling on Group III being synthetic was made by the National Advertising Division (NAD) of the Better Business Bureau and pertained only to a specific Group III+ being used by Castrol at the time. While hearings were held and expert witnesses testified, this was not a "court of law" and the decision was not legally binding. Marketers expanded the ruling to all Group IIIs knowing that no one would challenge it.
- The term "synthetic" refers to a process (synthesis), not the origin of the starting materials. The traditional definition of "synthetic basestock" as used for many years by the SAE prior to 1996 when they stepped back from the controversy referred to chemical compounds produced by chemical synthesis and manufactured by organic reactions from relatively pure organic starting materials. This is consistent with most dictionary definitions which define synthesis as the formation of a complex compound by the combination of two or more simpler compounds, elements, or radicals. By these definitions, PAOs, esters, and some Group III+ base oils would be "synthetic" (produced by synthesis) and regular Group III and below would not. However, a more common definition in wide use is that synthetic simply means "made by man" rather than occurring in nature. By this definition, regular Group IIIs would be synthetic since over 90% of the starting molecules are changed by man through hydrocracking, isomerization, and hyrogenation and did not exist in the original mixture. Arguing over which definition is more valid is indeed splitting hairs and an exercise in futility.
- Polyol esters are reacted from liquid fatty acids and solid polyol alcohols. The acids may be from either natural sources (coconuts, palm kernels, castor beans, tallow) or from petrochemicals derived from crude oil (olefins). The alcohols are generally made from petrochemicals derived from crude oil (acetaldehyde, formaldehyde, butyraldehyde). The reaction process is synthesis.
- Diesters used in synthetic lubricants are reacted from solid dibasic acids and liquid monohydric alcohols. Some of these reactants are made from natural sources (tallow, castor beans) but most are petrochemicals derived from crude oil. The reaction process is synthesis.
- PAOs are made from alphaolefins which are made from ethylene derived from crude oil. The process is synthesis.
- Some Group III+ would meet the traditional definition of synthesis since they are built up from smaller molecules. Most regular Group IIIs would meet the more common definition of synthetic (made by man) since existing molecules are broken and changed by the actions of man.
- Most synthetic motor oils are based on blends of Group III, Group IV, and/or Group V base oils. The manufacturers do not tell us which types are used or the percentages. Guessing is, once again, an exercise in futility.
While all of this may be meaningful to purists, from a practical standpoint all we should care about is how the motor oil performs in our engines under our driving styles and conditions. This information can be derived from approvals and certifications by industry groups and OEMs and from published physical properties.
Tom NJ