Redline oil, is this the best i can get??

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Originally Posted By: Tempest
Nope, seen it all before and it is still all opinion.


Well, yes, of course it is. However, let me turn it around for you. It's pretty easy to shoot darts at somebody else's observations, but let me ask you a question or two. What evidence do you have that synthetics offer more protection against wear than conventionals? And do you have any evidence to suggest that Redline is not a superior oil? (Something not sourced from one of their competitors would carry weight.) And out of curiosity, who is the number cruncher you referred to in your first paragraph?

I will go out on a limb here and disagree with your comments about boundary conditions however. I do believe that the physical resistance of the oil barrier to being breached is a critical element in overall wear protection. Consider this simple illustration. In any instance of boundary lubrication you could plot a curve, showing pressure vs. time, that would peak at a certain point. At the peak, any oil film would presumably have been breached and AW will be the primary method of protection for the metal surfaces. However, there will be a point on the y-axis, below the peak, at which the oil film's physical protection will give way to that AW protection (a slight simplification, but nevertheless illustrative). The total area under that curve will correspond to the wear potential of that boundary lubrication event, but the point on the y-axis at which the oil's physical barrier is breached will correspond to the oil's film strength under whatever conditions are present, which we can approximate with HTHS. It is easy to see that a slight raising of that y-axis point will raise the level at which the final, molecular-thickness, AW-barrier needs to come into play (activated by frictional heat on the breakdown of the oil barrier itself, of course), and would reduce the area under the curve very significantly. In fact, it stands to reason that some boundary lubrication events would be eliminated altogether with a sufficiently high HTHS, while all would be reduced in intensity.

In other words, it must be a combination of the oil's physical characteristics and the chemical AW layer that work to prevent wear, and the former must necessarily have a major impact on the need for the latter.
 
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I wish some independent entity would just do a bunch of actual controlled tests, similar to what Valvoline claims to have done, in real engines, with teardowns to determine actual wear.


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Consider this simple illustration. In any instance of boundary lubrication you could plot a curve, showing pressure vs. time, that would peak at a certain point.

Yes. This the realm of Friction Modifiers...an additive.
http://www.bobistheoilguy.com/forums/ubb...rue#Post1149776
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What evidence do you have that synthetics offer more protection against wear than conventionals? And do you have any evidence to suggest that Redline is not a superior oil?

I have suggested neither. IMHO, the base oil has little to do with wear in engines and I would have no problems running RL in my own cars as it is a quality product.

As far as HTST and base oil. Take a look at Amsoil 30 grades. The PCMO oils are 3.2. The HDD is 3.4, the motor cycle oil is 3.52, and the marine oil is 3.64...all with the same type of base oil.
 
HTHS is a measure of viscosity at a high temperature and high shear rate. At the given test conditions it is a function of the base oil viscosity, base oil VI, VI Improver quantity, VI Improver type, and other polymers. It is not a function of base oil film strength as the film is not broken in the test.

VI Improvers and some other polymers are "spongy" molecules that compress under high shear, causing the oil's viscosity to revert toward the Newtonian base oil viscosity. This test is designed to make sure that enough viscosity is maintained in the bearings to assure hydrodynamic lubrication under the given engine design.

Tom NJ
 
Originally Posted By: Tom NJ
HTHS is a measure of viscosity at a high temperature and high shear rate. At the given test conditions it is a function of the base oil viscosity, base oil VI, VI Improver quantity, VI Improver type, and other polymers. It is not a function of base oil film strength as the film is not broken in the test.Tom NJ


http://www.freepatentsonline.com/5646099.html

"exceptional film strength as measured by high temperature high shear (HTHS) viscosities..."

http://books.google.com/books?id=vkYCvwx...num=1&ct=result

"...authors emphasize the importance of HTHS viscosities as the factor controlling the hydrodynamic film strength..."

Just a couple found with a quick search. The correlation between HTHS and film strength is basic enough to be taken for granted.
 
Originally Posted By: Tempest
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Consider this simple illustration. In any instance of boundary lubrication you could plot a curve, showing pressure vs. time, that would peak at a certain point.

Yes. This the realm of Friction Modifiers...an additive.

No, it is the realm of AW and the oil's physical properties and the transition between them. Friction modifiers can be considered part of the AW package. This is from the link you supplied, forgive my attempt to replicate the formula with ASCII characters:

Total load support P = summation(asperites)P(sub)i + (integral over A)p(fluid)dA

In words, total support equals physical support from asperites plus fluid support from the hydrodynamic film. That is exactly the point I am trying to make. The greater the hydrodynamic support from the fluid, the less the need for physical support from the surfaces and the less the need for physical AW action.
 
Originally Posted By: Tempest
IMHO, the base oil has little to do with wear in engines...


Here is a quote suggesting the same thing with a very important caveat that goes to the heart of my argument:

http://books.google.com/books?id=vkYCvwx...num=1&ct=result

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Depending on the regime, additive chemistry or fluid viscosity control the wear. The ATFs contain additives to control the wear, and the base fluid (provided it is of low polarity) exerts little influence on the outcome.


So wear can be controlled well by AW only. No argument there. However, the base fluid is only unimportant "if it is of low polarity." This directly implies the correctness of my argument - that polarity is an important factor in wear when it is present, and whether it is present or not (and the degree to which it is present) will have an influence on overall wear protection.
 
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I am new to the site, and I have limited knowledge on motor oil.

All you guys talking about polarity and all, it lost me. . .

The way I see it is this:
Redline uses group V base oils = they use expensive base oils.
Redline uses high(er) end detergents = more expensive detergents.

Redline has to sell there product at a high price since it cost a high price to make it.

I do not see a point for redline to make expensive oils and limit there sales since its so pricy unless there oil(base and detergents) provide exellent results.

They (I would think) would not put out a product that dose not act like a 9 dollar oil.

No I am not being nieav (pardon my spelling)
Its just why would they waste there time on group V bases, ect. . . if there was no benefit. surly they could make a killer group III, or IV, but they must see something in there process. and it cant be money because (take a poll) not alot of people will dish out 9 bucks for a quart of oil.


HEY, this is just my 20 year old mind throwing ideas around. I know alot of you (from reading your posts old and new) are very knowing on the oil subject.

I cant belive we have these long conversations on motor oil!!!! LOL I love it.
 
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The correlation between HTHS and film strength is basic enough to be taken for granted.

Not sure if you know who Tom is, but you had better be ready if you are to question his knowledge in this area.

You may want to look at page #465 from the google link where is states that a PAO and ester mix is usually the ideal lubricant for ATFs. Including that esters can interfere with other additives.
And on page 470 (that you linked to) where they cite a study in which the same additive package was used in 4 different base oils with negligible difference in performance.
Pages 471 and 472 directly refute your entire assertion.
The summary on page 474 also is interesting.
Page 490 is telling to say the least.
Very good link bye the way.
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Friction modifiers can be considered part of the AW package.

NO. They each can exist without the other, and they have different functions and chemistries. AW is not necessarily a FM.
 
Hi Glenn,

I'll have to respectfully disagree with the gentlemen in your link.

Film strength is defined as the load or shear rate necessary to break the lubricant film and push the contact into a boundary regime. It is usually measured by a method that progressively increases load until the film ruptures, such as the Falex test, and the results are reported in units of load. Polarity has a strong influence on film strength since the ionic bond between the negatively charged oil molecules and the positively charged metal surface, as well as the intermolecular bonds within the oil, require more load to break. Esters are well known for their high polarity and film strength.

HTHS viscosity is defined as the viscosity under high temperature and high shear conditions. The test method is run at a constant load, not progressively increased, and the film is not ruptured. Results are reported in units of viscosity (Centipoise), not load. HTHS correlates to film thickness, but not film strength. Some may make the case that a thicker film is stronger, but the term film strength properly applies to the resistance to rupture through chemical bonding as opposed to a merely thicker film.

The HTHS viscosity test was designed to replicate conditions in the main bearings where temperatures and shear rates are quite high. The other viscosity test methods used for motor oils (Kinematic and CCS) are run at lower temperatures and shear rates and therefore do not predict film thickness in the bearings. This is important because multigrade oils are non-Newtonian due to the presence of large polymeric molecules, such as VI Improvers, and their viscosity changes with shear rate. Hence the quantity and type of VII makes the bearing viscosity unpredictable from Kinematic or CCS measurements.

Since bearings are designed to operate in a hydrodynamic regime, the oil film should not be broken and film strength will not come into play. If, however, abnormal conditions exist, such as over heating or excessive loads, and the film is stressed to the point of rupture, then film strength will play a role in protecting the bearings. Otherwise the benefits of film strength are generally seen in the cylinder area and some camshaft designs. By reducing the percentage of boundary contacts, high film strength can reduce friction and wear, although the effects may not be readily apparent under normal operating conditions.

The reason some oils have a higher HTHS than others of the same grade is probably due to the use of thicker or higher VI base oils, and/or VI Improvers with greater temporary shear stability.

Tom NJ
 
Thanks Tom for the great info.

Do you have any opinion on pure ester base stock vs. PAO/ester base and wear?

I think that some ester base stock is enough for "weating" and that you will get the same or nearly the same effect as full ester (in automotive lubricants).
Obviously, the types of esters matter greatly.
 
Hi Tempest,

Additive systems and seals are not designed for full ester based oils, and without an optimized add-pack it would be an unscientific comparison. A PAO/ester blend is cheaper and provides better seal balance than either base oil alone. The ester portion kicks up the lubricity and film strength a bit, but how much depends on the ester type & percentage.

On a theoretical basis the polarity of esters should provide advantages under some wear regimes, but since the AW & EP additives dominate wear control, it's kind of academic under normal operating conditions. I have always been reluctant to make a definitive claim of wear protection for esters, although evidence does suggest it.

There are some special esters that do contribute meaningful and measurable protection during oil starvation conditions through superior film strength, even at percentages under 10%, but I am not aware of anyone using them these days.

Tom NJ
 
More good stuff there.

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There are some special esters that do contribute meaningful and measurable protection during oil starvation conditions through superior film strength, even at percentages under 10%, but I am not aware of anyone using them these days.

Don't know if you can say, but why not? Cost? Enviro? Seals?
 
So then, we all agree, Redline is a superior product that stands above the crowded oil shelves along with Neo and Motul 8100 ester based oils?
 
It's mainly a question of cost versus return. The cost is relatively high, and return comes in the form of a marketable claim. The main claim - protection under oil starvation conditions - had its day when one major used this technology in the 90s. Doesn't seem to be too popular these days.

Tom NJ
 
I don't make any claims of one product being superior to another. First, it depends on the engine, driving conditions, and driver habits. Second, without knowing the full formulation and reviewing all the test data, I am not qualified to judge performance. And running an oil in my car doesn't help, unless I do 100,000 miles under carefully controlled conditions, followed by a full engine tear-down. Superficial observations such as higher MPG and smoother operation are unscientific and subjective.

The "quest for the best" journey often leads to expensive frustration.

Tom NJ
 
I am going up monday to the shop to buy the oil, I am going to use a Pure One filter, and we will see how it goes.

If I dont write on this board after monday, that means the Redline has Blown up my car and I am burning alive in my car at the bottom of a cliff.
Tell my mother I love her. . .
 
My '97 Camry V-6 is one of the infamous sludge monster engines. I've driven the engine very hard through a 5-speed manual transmission. It had never shown any signs of sludge, but I played it safe and ran two cycles of Auto-Rx at 104,000 miles.

I've run Red Line 5W30 since that time. At 201,000 miles, I asked the Toyota mechanic to adjust the valves for me. He made the unsolicited comment that the inside of the engine looked as clean and unworn as a car with 20,000 miles.

The "value" people will always attack Red Line. The "results" people like me and rg200amp will just laugh and keep using it.
 
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