Originally Posted By: SonofJoe
The idea that 'wear' in general is primarily dependent on aggregate base oil viscosity (as opposed to VII 'enhanced' viscocity) has been around for yonks. IIRC, some of the industry standard wear test read-across tables are predicated on this principle.
Having said that, I'm not sure if I buy into the theory. If VIIs were to shear away to nothingness, I might agree, but it never does. Even high SSI VIIs (especially OCPs) are, in real life, remarkably robust. You have to remember that OCP VIIs contain a broad, bell-shaped distribution of polymer chains and only the very heaviest shear down.
Also the idea that VII polymer chains are in some way 'squeezed out' of tight gaps, and so cannot influence wear, seems to me fanciful. An expanded polymer chain, with all those surrounding, occuled base oil molecules would be indistinguishable from base oil itself. What next? Do additive molecules like Ashless & ZDDP get "squeezed out', in which case I completely wasted 13 years of my working career!
Talk to oil formulators and whatever Nissan might say, the prevailing view is that timing chain wear is impacted by chain metallurgy & manufacturing way, way more than oil quality. Yes they still have to run & pass the requisite CW tests and yes, they probably claim great results for 'their' oil but in their hearts, do they truly believe this to be the case? I think not...
I agree..
the concept of HTHS came about because the 10W40s of the day were utterly hopeless, and didn't live up to their kinematic grade in terms of protection.
When they started messing around, they found the "apparent" viscosity, which later became the HTHS...which even with VII is still greater than the BOV.
The Nissan paper, I think when comparing the same base oil viscosity for the same outcome, I think is confusing the "apparent" high shear viscosity.
Timing chains aren't hydrodynamic, as the motion in them is only over a partial arc, then reversal at every change of direction...they don't get to form a wedge.
Which means that they are probably predominated by squeeze film separation (oil gets between surfaces, and when the load is applied, has to get pushed out the sides, resistance to that holds the surfaces apart until contact is made...a 60 tonne generator shaft 20"dia 19"long bearing takes over half an hour to settle on brightstock to the point that the alignment can be trusted).
Timing chain wear is typically considered three body wear, it's not surface to surface, but surface to particle to surface, the particle acting on both surfaces...keep the squeeze film thick enough, and the particles don't get trapped.
Diesels, harder "soot" particles need more separation forces.
Gassers, smaller and softer soot, can live with lower viscosity.
Friction modifiers FTW in both cases, which is pretty much what Nissan said.
(note that part of their testing was at controlled oil temps of 50C...they did that for a reason.)