Charging Algorithms for Increasing Lead Acid Battery Cycle Life for Electric Vehicles
Valve regulated lead acid (VRLA) batteries have been developed primarily by companies that also manufacture flooded lead acid batteries. Thus, the VRLA products are charged similarly to those traditionally developed for flooded lead acid technology. The dominant charging method used is current-limited constant voltage (CV). Some manufacturers recommend two- step constant current (CC) or some combination of CV and CC (e.g., the European IUI approach). All these approaches are characterized by their use of some fixed overcharge level, usually 10%–20%, that can act as a secondary charge-termination limit in conjunction with a fixed termination method throughout cycle life (e.g., time or voltage).
Regardless of how VRLA batteries are charged in electric vehicle (EV)-type duty cycles, the life to 80% of initial capacity is usually 200–300 cycles. This is probably due to the lack of compensation for the changing role of the oxygen-recombination cycle in the ways most VRLA batteries are charged.
Beyond the obvious differences in plate chemistries, the charging characteristics of VRLA may be closer to those of sealed nickel-cadmium (NiCd) products than to flooded lead acid. Both VRLA and NiCd operate on oxygen-recombination to minimize water loss, whereas flooded lead acid does not. The extreme depolarizing effect of the oxygen cycle must be taken into account in developing charging strategies or the negative plate will fail early because of sulfation. NiCds are charged almost exclusively with CC methods and typically have overcharge levels of 40%–50% at room temperature. Their termination strategies are linked to sensing cell parameters (temperature, voltage/time changes) and not to a fixed time or overcharge level. This is easier to do with NiCd because overcharge is less harmful than for VRLA. NiCd cells cannot be charged using CV or even low-level CC because much of the finishing current is consumed by the oxygen-recombination cycle. The oxygen- recombination efficiency (ORE) is much greater for NiCd than for VRLA because of differences in the basic designs, but for flooded lead-acid the ORE is basically zero. A major key to understanding how to properly charge VRLA batteries in cyclic applications is that, in terms of charging behavior, they are more like NiCds than flooded lead acid. Therefore, looking at how and why NiCds are charged is useful.
Another key is to acknowledge that, unlike flooded lead acid or even NiCd products, VRLA batteries experience significant changes in electrolyte distribution as they age in deep-cycling applications such as EV duty. Early in life, they are almost flooded, and could probably be charged like a flooded product. However, as a VRLA battery ages it loses water because gases are vented and water vapor is transported through the plastic case. Also, water is consumed in the grid-corrosion process and electrolyte redistributes from the separator in the plate pores. These factors contribute to an increase in void space in the glass-mat separator that results in an ever-increasing ORE, which has an enormous impact on charging. In traditional CV and CC charging approaches, this increase in the role of oxygen recombination is not taken into account. Thus, another key to properly charging VRLA batteries is to either modify the charging/termination algorithm throughout the cycle life or charge them in such a way that these changes occur more slowly.
If such a modified algorithm is not used, a VRLA battery will invariably reach a point in cycle life where the oxygen-recombination cycle consumes most or all of the overcharge current allowed by the charge. Thus, a proper finishing charge for the battery cannot be delivered. As the battery ages and the ORE increases this becomes more and more pronounced. The result is a “walk-down” of capacity when the allowable overcharge amount (e.g., 10%–20%) cannot support the oxygen cycle.
Given these findings, and work already carried out in the ALABC program (3), we feel that a proper charging algorithm for VRLA batteries involves the following:
- • High inrush currents to promote nucleation, thus maintaining a fine, open pore structure.
- • No limitation on the percent overcharge (although, with proper charging and termination,
this should never exceed ~20%).
- • A modest-to-high rate of charging to provide current to the battery fairly rapidly, particularly at the beginning and end of charge.
- • High finishing currents to provide enough charge for the recombination cycle and still have some available to finish charging the active materials.
- • An effective charging termination point that completely recharge the active materials with minimal overcharge and compensates over the battery lifetime for the increasing influence of oxygen recombination.
Conclusions and Summary
Conclusions for the Zero Delta Voltage (ZDV) charging technique on Optima VRLA battery are:
- • Applying a ZDV technique similar to the one used for NiCd batteries, we were able to increase the cycle life of the Optima VRLA by a factor of 2.
- • As VRLA batteries age, increasingly higher finishing currents are drawn because of the oxygen cycle; the charge/termination algorithm must be adjustable to respond to this. A fixed, monotonic algorithm will result in overcharge early in life and undercharge later in life.
- Conclusions from the 24-module battery pack cycling using a current interrupt [CI] technique are:
- • Applying the multi-step CC/CI charge algorithm without battery management results in excellent pack cycle lifetime for the Optima product.
- • Insufficient recharge of 12V modules in a large pack appears to be amplified relative to single-module cycling.
- • Weight losses are very low, on the order of 100–150 grams, suggesting that “dry-out” is not a failure mode.
- • The small differences between initial and final OCVs and impedances indicate that negative-plate sulfation is not severe.
- • There appears to be no clear correlation between operating temperature and failure; however, warmer modules appear to have longer lifetimes.
Using these types of charging algorithms can apparently increase the life of VRLA batteries for EV applications by a factor of at least 3.