It's been a whirlwind 24 hours. I'm coming up for air now.
This is a summation of Dr Rudnick's work in Lubricants and Lubrication (2nd ed) and also Lubricant Addtives: chemistry and applications. I was able to then ask a bunch of questions and dang if it wasn't mind-blowing in several ways. Because the conversation included so many references to specific chapters and pages of these works, I feel like a got a pretty good Cliff's Notes of these enormous volumes. I suppose perhaps the AI was gaslighting me the entire time, and I am just that gullible. But it all made sense to me as explained.
What I found most mind-blowing of all, however, was the suggestion that the modern epidemic of sticking rings might have more to do with oil oxidation and little to nothing to do with "low tension rings." After all, here on BITOG it's mostly accepted as gospel that modern engines all have "low tension rings" and these rings all suck and that's why all new engines are junk and turn into oil burners.
But what is the *mechanism* by which being lower tension would cause the rings to develop deposits? Lower tension also means narrower in thickness. The result is that the rings have lower tension because they don't need as much tension to generate the same outward sealing pressure values. "Low tension" as a standalone explanation for piston ring groove deposits and resulting oil consumption is just wholly unsatisfactory as an explanation.
So what is actually contributing to the epidemic of stuck rings?
[edit by moderator - AI image removed]
The analysis continues as follows:
So what does this suggest to me?
It suggest to me that the modern problems with ring sticking have perhaps nothing to do with "low tension" rings. But, like low tension rings, it is in fact a product of the government mandated push for CAFE and enhanced fuel economy, but ring sticking is a phenomenon of oil oxidation in the ring pack, and low HTHS oils are much worse for ring pack oxidation. If the oils below 3.5 HTHS are 25-40% worse in ring pack deposit simulations than oils that are >4.0 HTHS, then how much worse are these oils that are 2.7-2.8 HTHS in ring pack oxidation?
In other words, we seem to be mistaking correlation for causation-- that because "low tension rings" coexist with low viscosity oils and sticking rings, that the the ring sticking is *caused* by the lower tension. However, the low tension may just be coexisting with the lighter oils, which may be the real contributor to stuck rings. Especially so in dilution-prone GDI or TGDI engines where the ring pack films are even more heavily compromised by dilution that can be double what the sump dilution is.
I never considered viscosity and cleanliness to be related in this way. But I'm seeing in the "Rudnick commentaries" many smaller ways in which thicker oils lead to cleaner, happier engines-- less tendency to generate crankcase aerosols (huge for GDI), thicker films which are actually very useful at light loads, etc.
This is just one of the many aspect of this deep dive with "Dr Rudnick" that sort of blew my mind, but it was by far the most consequential, in my opinion. If anyone wants me to share other insights from this deep dive with "Dr Rudnick", just say the word and I'll put those in another thread.
This is a summation of Dr Rudnick's work in Lubricants and Lubrication (2nd ed) and also Lubricant Addtives: chemistry and applications. I was able to then ask a bunch of questions and dang if it wasn't mind-blowing in several ways. Because the conversation included so many references to specific chapters and pages of these works, I feel like a got a pretty good Cliff's Notes of these enormous volumes. I suppose perhaps the AI was gaslighting me the entire time, and I am just that gullible. But it all made sense to me as explained.
What I found most mind-blowing of all, however, was the suggestion that the modern epidemic of sticking rings might have more to do with oil oxidation and little to nothing to do with "low tension rings." After all, here on BITOG it's mostly accepted as gospel that modern engines all have "low tension rings" and these rings all suck and that's why all new engines are junk and turn into oil burners.
But what is the *mechanism* by which being lower tension would cause the rings to develop deposits? Lower tension also means narrower in thickness. The result is that the rings have lower tension because they don't need as much tension to generate the same outward sealing pressure values. "Low tension" as a standalone explanation for piston ring groove deposits and resulting oil consumption is just wholly unsatisfactory as an explanation.
So what is actually contributing to the epidemic of stuck rings?
[edit by moderator - AI image removed]
The analysis continues as follows:
**The Oxidation-Deposit Pathway Leading to Ring Glazing**
Rudnick dedicates much of Chapter 9 to oxidation and nitration tests (e.g., ASTM D943 for oxidation stability, D6594 for nitration), explaining how low HTHS exacerbates these to form deposits on piston rings. Here's the mechanism:
- **Thinner Films = Higher Temperatures**: Low HTHS allows more asperity contact, raising interfacial temperatures beyond the oil's thermal stability threshold (~150-200°C for synthetics). Rudnick notes that oils with HTHS <3.5 mPa·s oxidize 20-30% faster under shear than >4.0 mPa·s grades, as measured by pressure differential scanning calorimetry (PDSC) induction time (Ch. 9, pp. 200-205). In your engine, this manifests during cold starts (~150/year) or urban transients (25% duty), where the fixed-gear pump's initial ~15-25 psi flow can't quickly rebuild films.
- **Acid Buildup and Varnish Formation**: Oxidation produces carboxylic acids (measured by TAN, total acid number), lowering TBN reserve and catalyzing further degradation. Rudnick highlights nitration (from NOx) as a GDI-specific culprit, forming nitro-compounds that condense into lacquer-like varnish on ring faces and grooves. Low-HTHS oils exacerbate this by promoting blow-by (unburned fuel/oil mist), which dilutes the sump and thins the oil further, trapping varnish precursors against hot ring lands.
- **Ring Glazing Mechanism**: Varnish hardens into a glassy carbon layer (glazing), smoothing the ring face and reducing its scraping action on the cylinder wall. Rudnick ties this to TEOST-MHT (Thermo-Oxidation Engine Oil Simulation Test, ASTM D7097), where low-viscosity oils score <80 merit for piston deposits—indicating glaze-prone varnish buildup. In turbo-GDI engines like yours, this glazing impairs sealing, leading to blow-by escalation (lost compression, ~5-10% MPG drop) and accelerated wear (Fe/Al rise ~20% in used oil analysis). Rudnick quantifies: oils with HTHS <3.5 mPa·s show 25-40% higher deposit weights in ring-pack simulations vs. >4.0 mPa·s (Ch. 9, pp. 210-215).
So what does this suggest to me?
It suggest to me that the modern problems with ring sticking have perhaps nothing to do with "low tension" rings. But, like low tension rings, it is in fact a product of the government mandated push for CAFE and enhanced fuel economy, but ring sticking is a phenomenon of oil oxidation in the ring pack, and low HTHS oils are much worse for ring pack oxidation. If the oils below 3.5 HTHS are 25-40% worse in ring pack deposit simulations than oils that are >4.0 HTHS, then how much worse are these oils that are 2.7-2.8 HTHS in ring pack oxidation?
In other words, we seem to be mistaking correlation for causation-- that because "low tension rings" coexist with low viscosity oils and sticking rings, that the the ring sticking is *caused* by the lower tension. However, the low tension may just be coexisting with the lighter oils, which may be the real contributor to stuck rings. Especially so in dilution-prone GDI or TGDI engines where the ring pack films are even more heavily compromised by dilution that can be double what the sump dilution is.
I never considered viscosity and cleanliness to be related in this way. But I'm seeing in the "Rudnick commentaries" many smaller ways in which thicker oils lead to cleaner, happier engines-- less tendency to generate crankcase aerosols (huge for GDI), thicker films which are actually very useful at light loads, etc.
This is just one of the many aspect of this deep dive with "Dr Rudnick" that sort of blew my mind, but it was by far the most consequential, in my opinion. If anyone wants me to share other insights from this deep dive with "Dr Rudnick", just say the word and I'll put those in another thread.
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