Originally Posted By: Volvohead
The hygroscopic nature of most fluids (except the silicone based ones) certainly helps disperse it some. But if you ever played the conductivity test with the first shot out of a bleeder valve, the values there are much higher than what you'll see at the reservoir in many instances. That's why I don't trust the meter test up top.
All that absorbed moisture does in the upper system is corrode and wear parts.
In the lower end, it causes braking failure and accidents.
I'm coming from a garage and field perspective. But DOT 4 fluids also tend to be more prone to hygroscopic failure than the old DOT 3 types, according to folks more educated on these matters than I. That may also explain why today's high performance braking systems sometimes can't go on for 10 years on the same fluid like a '75 Caprice might have.
These folks have a nice little white paper that does a fair job on the various fluid types and how boiling points become compromised:
http://www.stoptech.com/technical-support/technical-white-papers/brake-fluid
The bottom line is that the worst condition fluid generally is at the bottom of the system, where conditions are the harshest.
V-H
Its nice to know that someone actually has tried to measure a difference between the fluid in parts of the brake system. This is the first evidence I've seen that there may actually be a difference. But without a plasible explanation, this still sounds, to me, more like unchallenged folk-wisdom than anything else.
Maybe even effect-cause thinking as opposed to cause-effect - "The fluid at the wheel boils first, therefore it must be the worst" (ignoring that that is the only place where heat is applied).
Even the paper you cited mentions only the M/C as a potential point of concern re moisture entry.