As big of a Red Line fan as I am, Shockproof is not really a great street fill. I played that game in the Subaru community and you'd certainly be better served by a top shelf "traditional" gear oil. The longevity isn't there and there are rumors it doesn't handle moisture (including humidity?) very well.
On the ZF8- Usually agree there are better fluids than OEM, but in this case the evidence just isn't there that we "need" something else. Ended up just throwing Lifeguard 8 in mine since failures are so uncommon even without servicing them. In the future I may use aftermarket ZF8 specific fluid (Ravenol, Pentosin, etc.). The key here is friction coefficients and that would be really hard to figure out.
Back to the transfer case- there is a known longevity problem here unlike the ZF8 so it's only natural to try "curing" it. Not a pro mechanic who sees these cars daily of course, but clutch problems seem to be the usual issue, and regular changes with matching tires are the likely solution. My 3-series ate it's transfer case at 165k mi after the prior owner put mismatching tires on it...doubt it ever had a fluid change, though clearly they can last a long time. Same as the ZF8, friction coefficient is very important for the clutches and I ended up removing the MT-LV in favor of Ravenol DTF-1 while doing other maintenance.
In theory xDrive transfer cases are nothing special compared to other active transfer cases which take ATF, etc. but we have no idea why the manufacturer has specified this fluid. While the viscosity and additives may look like MTF, the friction properties could be wildly different. Surely if they could consolidate supply chain/stock into one fluid they would have.
Hyundai/Kia/Genesis specify TF0870 as well since they also use Magna ATC units like BMW. VW/Audi/Porsche appears to use a few different fluids depending on model and year, but have not investigated into hardware differences.
Also agree to avoid any N20 prior to April (I think) 2015 build date due to the timing chain disaster- unless it's been replaced or you want to replace it. My local BMW independent mentioned having some cars which are in for their second chain replacement, but it's unclear if the first replacement was with the updated parts or not.