Nature doing nature things and the little buggers will be blended fairly quickly.
Blackstone labs used to ask for their samples to be taken hot after taking it around the block a few times, but they removed that from their instructions.
Here is the link from 2021, and their current link. Excerpting here for easier reading.
2021
"Run the engine before you take the sample to get the oil at operating temperature (driving about 20 minutes should do it). Getting the oil up to operating temperature should help cook out any moisture or fuel build-up from the last time you drove. Then let the engine cool down a bit before you pull the sample. We don’t want you to get burned, and we don’t want to melt the tubing if you’re using a quick-draw pump to pull the sample."
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Gas & Diesel Sampling | Blackstone Laboratories
web.archive.org
Current
"It doesn’t matter if the oil is cold or hot when you take a sample. Just try not to start the engine immediately prior to sampling. Even if you do though, it’s not a big deal. Just let us know."
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Gas & Diesel Oil Sampling Procedure | Blackstone Laboratories
Gas or diesel engine oil sampling is easy with Blackstone's free oil analysis kit. Here's how to do it!www.blackstone-labs.com
I'm mildly curious about what caused them to change their sampling procedures, knowing them its probably backed by data.
They probably changed it to hot or cold because they think it doesn't matter as long as the sample is taken mid-drain point as their following statement says:
"If you’re changing the oil, try to pull your sample from the middle of the drain. The first oil out might have some dirt from around the drain plug. If you wait till the end, you might not have enough oil left to fill the bottle."
Although, IMO if it was done shortly after warm or hot engine shutdown vs cold there might be slightly more suspended particles that the oil filter couldn't filter out. If someone was doing a particle count with their usual UOA to say compare filter efficiency impact on oil cleanliness, I'd suggest doing a warm/hot drain for the UAO. Without an added particle count on the UOA, it wouldn't matter if the sample was taken hot or cold. A normal Blackstone UOA doesn't include an ISO particle count. If Blackstone was more detailed in their instructions, they should probably say if you want a particle count of the UOA, then the sample should be taken warm/hot shortly after engine shutdown.