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though it seems that "synchromesh" is a viscosity range.
Synchromesh is not a viscosity but a type of gear engagement system for manual transmissions.
The two fluids can be mixed to get the viscosity you need by experimentation.
They contain the same synchro friction modifier compounds and similar Anti-Wear additives; just different viscosities of base oils.
MTL or MTG can used in all kinds of synchromesh-type transmissions that use low or high viscosity fluids.
Historically, I think the reason the lighter fluids has been seen as the "synchromesh" fluid is that GM's original synchromesh fluid had a viscosity of about 9.5 cSt, so any MTL between about 9.0 cSt and 11 cSt is seen as a synchromesh fluid. And then of course, Pennzoil and Texaco picked up on it with a similar fluids.
Many VW and Toyota transmissions require a 75W90 fluid but have synchromesh type ystems as well. Even some of the heavy duty truck transmissions have synchromesh type systems as, but may use 50 weight oils.