The Nissan "Ester" oil contains only about 1% of an ester type friction modifier because of a special DLC coating they use. Redline says their ester formulations are blended with PAO.
As base oils, properly selected esters will excel in oxidative stability, volatility, lubricity, cleanliness, and additive solubility compared to PAOs, but I would be concerned about seal compatibility in a 100% ester based formula. Furthermore, these base oil "property advantages" do not translate into real world "performance advantages" for most users, and additives may trump base oil differences. Not saying base oils mean nothing, just not everything.
The best base oil for you is the one that best meets your individual needs, including cost, and for most people that is a blend.
Tom NJ