How are they fired? Is there a switch or button on the control stick? It would seem that they would be used in a high stress situation. Is there a type of, "arming switch" that is activated first?
The buckets are armed when a safety pin is pulled during the launch (on the ship, it's when hooked up to the catapult, at the field, it's when you're in an arming area, right next to the runway, same place where we armed bombs, or guns, or missiles).
I think it was just one pin for both buckets. The weapon system would inhibit firing weapons if there was weight on wheels, and I'm pretty sure it was true for expendables, too. So, it would be armed, but not available, until the airplane was airborne.
Dispensing them depended on what was programmed. A control panel in the back set the "program" - how many and which kind were coming out.
There was a button on the left side of the stick, under the pilot's thumb, that would dispense a "program". The RIO had two multi position castle switches (cones, with four directions of activation) on the grab handle at the top of their displays. Both switches had the same function, but there were two, so that the RIO could look over either shoulder, and still be able to put their thumb on a switch.
I don't remember the directions, exactly, but one direction would dispense a program, and another would dispense a single round of a specific type, depending how that arming panel was set up.
There were Standard Operating Procedures for who dispensed what, and in what circumstances. If you were putting out, say, 10 rounds in a program, then you could run out of expendables quickly if both the pilot and RIO were punching their respective buttons. I think we used to say that the pilot would dispense flares for an IR missile defense, which makes sense, because the pilot knew when the airplane was out of AB (to help with the decoy - the AB plume was huge and hot - you wanted it gone before using flares).
And the RIO would put out the ECM for a radar guided missile, while the pilot was maneuvering the airplane. The timing of putting out the other stuff depended on missile range, closure, and aircraft maneuvering, so, RIO is watching over their shoulder, executing the timing, while the pilot flies.
One exception to the rule - the ECA (Expanded Chaff Adapter) - it worked using the bomb button (since it was on a weapon rail, the firing pulse came through the stores management system, not the normal expendables system), and only the pilot could drop bombs, so the pilot put out all the ECA rounds.