In some designs, the vapor canister IS the vent for the gas tank.
It provides 2 important functions:
1 - It takes any gas vapor, routes it to the charcoal canister, where it then gets ingested by the engine when the canister purge valve is activated, and the fumes are pulled into the intake stream.
2 - It acts as a vent for the gas tank to allow fresh air into the gas tank (usually through a small filter) as the fuel is consumed by the motor and the level decreases. Otherwise, your gas tank would implode as the fuel level goes down.
I just recently had to pull the rear seat out of my friend's 2013 Fiat 500 (over 100k miles) and give the vent valve a good whacking in order to allow her to refill the gas tank without the gas pump from shutting off every 3 seconds. She had been putting up with it for months before she mentioned it to me, and in 10 minutes, and a couple of hand tools, all was better.