The Colonial Pipeline ships most of the gas around here, it is 85 octane, with no additives in the pipe.
Once at the distribution facility, the first cut is usually 10% Ethanol, to give you 87.
More octane boosters are added to get to midgrade 89, and 92/93....
88 octane gas is 85 with 15% Ethanol added, its cheaper because of the Ethanol kickbacks from the Feds.
Additives are shipped through tanker truck, rail, or ship, because they would damage the pipeline....
Each customer has their own blend of gas additives, but the difference can be as little as a quart can of detergent, added to a tanker load.
Some blends have less Ethanol, and more of other octane boosters...