Originally Posted By: zeng
Originally Posted By: SonofJoe
VII polymers in engine oil will shear when subjected to mechanical stress and lose part of their functionality.
Is there a likelihood in high shear areas like differential hypoid gears and cams/lifters or any other applications , VII completely lost its viscosity contribution temporarily ?
What about permanently lost its viscosity contribution.
Btw, can base oil operating at high temp and high shear, temporarily lost its viscosity?
There are time elements to the rheological behaviors of a fluid. These have to do with the chemical characteristics as well as the physical characteristics of the fluid. Very interesting research area, especially for other polymer industries, like spinning of fibers that have fine particles or other polymers dispersed.
I think that for oils, the key thing to remember is this - VI is purely a viscosity/temperature correlation. Easily defined as a ratio for various temperatures, and offering no specific basis for shear-induced phenomena which can affect the viscous behaviors. This comes back to the comment early on in this thread that mentioned that junky 10w-40 oils (made with a ton of VII) were not protecting as their viscosity would suggest.
Polymeric additives behave a certain way. They are all tangled up as long, high molecular weight chains (think worms or snakes entangled). Recall how I said that VI is purely a temperature phenomena? So for a given stress, the viscosity at different temperatures may vary in some way. And that gets reported, and all is well. But it's not the whole picture... Over time, those polymers can not only shear and straighten out (equating essentially to lower viscosity/higher flow with the same pressure drop), but they also break, chemically degrade, and for certain time constants and scenarios, slowly return to their tangled form, sometimes fully, sometimes not. It's the sometimes not that is an interesting research area and which relates to what you ask.
So that's really the point of HTHS. VI isn't sufficiently indicative, going to a higher temperature doesn't properly indicate the "uncoiling" phenomena of VIIs and other additives, both from the perspective of shear-induced viscosity changes, along with the time and chemically-related relaxation parameters inherent in the fluid. Situations where the VII won't necessarily immediately fully re-coil, yet it also does not stay fully straight and unimpeding to the fluid characteristics. The basis of various hysteresis and time phased phenomena is directly related to why we must study other characteristics to define what a fluid actually looks like under more severe use.
The matching of VII to base fluid, the thermal and viscous response of that fluid and mix, etc. all come into play. Simple enough to blend and get some top level characteristics, but more difficult to fully optimize for sustained viscosity enhancement, etc.