My understanding about dielectric lube(silicone lube) is that it is not that it has anything in it to help with better electrical contact. It's just the opposite, It doesn't have anything in it to prevent good contact, is a great lube and also a very good moisture barrier.
Silicone pastes/lubes(e.g. brake lube) are similar however, they may have ingredients/chemicals in them that could prevent that wanted better electrical contact. And silicone product won't deteriorate rubbers & plastics.
Petroleum product or anti-seize products aren't the optimal products for these components however, I know tons of folks who do indeed use use them for things such as battery posts, brake sliders, electrical contacts etc.