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You guys really need to read Gao et al, SAE 2003-01-3119. ConocoPhillips and Ford engineers tested 5W-20 oils with different levels of ZDDP using a laboratory valve train bench test that employed constant monitoring of a radioactive tracer embedded in the metal as well as wear scar measurements. In a number of tests, they compared fresh oil with the same oil after 12,000 of engine service using both fresh and broken in metal surfaces. Their results show pretty conclusively that the anti-wear properties of an oil improve with age. They speculate that the increase performance could be due to accumulation of high MW oxidation products of the base oil or intermediate reaction products of the anti-wear compounds. Nobody understands why this happens, but a reduction in wear rates as oil ages seems to be an empirical reality. As I have mentioned elsewhere on this board, neat little models that try to explain anti-wear surface chemistry and the interaction of various boundary lubricants, friction modifiers, and metal surfaces are just speculation. These chemistries are complex and not well understood.