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lazaro, it can if the analyst or lab is stupid,disinterested,ignorant,using poor quality test equipment etc.
Most of standard ICP or AA spectro testing protocals will reveal (when properly interpreted) signs of problems even when larger particle detection or ferrography is not employed. It's why for our customers (professional or consumer level) we begin with our low cost Premium Service. The chance of a large chunk of material metal or not breaking off and the 10um or less level of spectral detection NOT seeing it is small.
Does Spectral analysis miss things, sure, however the total test result if using a broad battery of basic tests in addition to wear metals can alert the experienced analyst that odd results need to be explored further.
This is where science,service,and smarts cross and we care enough to provide that for every customer the best we can.
Terry