ZDDP history

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Greetings... This may have been discussed before but I couldn't find a thread about it. How long has ZDDP been used in motor oil. Is there a patent date covering its use? I suspect it is about mid 70's. TJ
 
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I won't cheat and will go off my memory: 1940s? A Google search should tell you. I'll check back here later and see how good my memory is.
 
Since hypoid style rear ends replaced chain drives in trucks. Can't remember the year either. I believe it started in gear oil 1st.
 
When did ZDDP start showing up in API service grade oils?

SA - Straight mineral oil.

SB - Minimal wear protection requirements

SC - 1964 Model year requirements

BTW - This is a very good topic, of general historic interest to everyone!
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