A terminal clamp and post interface is about making sufficient contact to allow the flow of current. Grease will not impede this flow in any significant way even if both, the terminal and clamp surface, are a bit rough but clamped together tightly. Also, the terminal post is made from very soft metal that allows for excellent contact-making.Why does oil leak from a properly tightened drain plug? The parts don't fit together perfectly at microscopic levels so the grease will migrate into the space.