Hi.
Ethanol is an oxygenate that is used in gasoline to reduce emissions by facilitating more complete combustion. The reason why some vehicles may experience decreased performance is because an oxygenate by definition introduces more oxygen into the fuel-air mixture. This shifts our excess air factor (lambda) to the right, forcing a reaction that is what we could term "lean burning." Lean burn is not favored by some vehicles because they are optimized to run a slightly richer (lambda < 0) fuel-air mixture for increased power, better driveability, and lower NOx formation. Of course, this comes at the cost of increased CO and CO2 emissions. A catalytic converter can be used to reduce both of these emissions.
Anyways, Top Tier gasoline has to be certified to obtain that rating. This is at the discretion of a group of automakers. It's a guarantee that you will get high quality gasoline. However, just because it doesn't carry that certification doesn't mean it's not high quality. It's just they do not want to, or have the assets to pursue, that certification.
It's perceived that pure gasoline is better for your engine instead of being oxygenated with ethanol. That's an incorrect assumption. Ethanol increases the enthalpy change of combustion (delta H more negative) of a gasoline mixture. So you get more energy = more power. However, the car's engine has to be able to handle the increased temperatures and energy. Most cars cannot, so it's perceived that ethanol lowers power. Likewise however, most cars also experience lower fuel economy because ethanol typically burns faster. Although it produces more energy. That's the simple answer, but it gets more complex.
Of course there will always be exceptions.