DC doesn't travel well over long distances.
Edison wanted DC to be the standard so he could have a (presumably licensed) power generating plant every 2 miles.
If you double the voltage and halve the current, you get the same work done, but need less copper in the conductors. This inspired cars to go from 6 volts to 12 in the 50's and is inspiration for the 36/42 volt systems proposed. Apparantly the Prius runs yet higher voltage but has safeguards in place due to the >50 volts being "more dangerous".