Originally Posted By: CaspianM
Can you explain how octane can change the af ratio? I would like to know.
Well, octane won't.
But in a carburated engine, the engine produces vacuum that pulls the fuel through the jets.
As the specific gravity of a fuel changes, so will the amount of fuel that gets into the cylinder. So, everything being equal, pump gas has a specific gravity around .755. Most 110 leaded racing fuels are in the .710 to .730 area. If one just changed the fuel, it would be richer as more fuel would be pulled into the combustion chamber.
Oxygenated fuels are available. A lot of pump gas has oxygenates too from ethanol to MTBE. The addition of those additives further leans out AF mixtures.
A common 110 leaded is NOT oxygenated. Some unleaded racing fuels that are easily available have some oxygenate at times.
Lead is available in some fuels. Really, the aromatics and the lead in those fuels can be a benefit when added to pump gas in that 75% pump gas/25% race fuel. Unleaded fuels burn a bit scattered, but when lead is introduced, it usually will contribute to a more uniform flame burn. That can lean out the mixture a little as the AF in the combustion chamber is burned more so than just an unleaded.
Given that one's jetting is "correct", I'd start by cutting the pump gas with a little 110 leaded fuel. The overall mixture will end up having a little lighter specific gravity, have a little lead, and have a little more of the aromatic chemicals that have been pulled out of fuel. It should allow for a little better burn in the cylinder without changing jetting.
Hope that gives you some ideas.