At this age and mileage, I'd find all the injectors suspect
New ones are ~$50 or so
Maybe remove them all and send them for cleaning/flow testing?
Or just replace the one
Of course, a fuel filter and a bottle of Techron wouldn't hurt
A leak down test would isolate a valve issue, of which Vulcans are somewhat known for
If it's still on the original Cam Synchronizer, swap it for a Motorcraft unit, check to make sure the cam sensor didn't get mangled by the tooth on the synchronizer
IAC not sticking?
Not high enough mileage for timing chain stretch?
Inspect the Coolant temp sensor, I remember my Vulcan Taurus being kinda fussy about the OE Motorcraft part
New ones are ~$50 or so
Maybe remove them all and send them for cleaning/flow testing?
Or just replace the one
Of course, a fuel filter and a bottle of Techron wouldn't hurt

A leak down test would isolate a valve issue, of which Vulcans are somewhat known for
If it's still on the original Cam Synchronizer, swap it for a Motorcraft unit, check to make sure the cam sensor didn't get mangled by the tooth on the synchronizer
IAC not sticking?
Not high enough mileage for timing chain stretch?
Inspect the Coolant temp sensor, I remember my Vulcan Taurus being kinda fussy about the OE Motorcraft part