The paint marks may not be relevant at all in this case. When was the manual written in relation to this specific engine? Does this actually apply to this engine? OEs are guilty of being lazy and copy/pasting too - I've seen it a few times. Is this the same manufacturer of rings that was used when the manual was written?
What does matter is that the rings are installed according to their design. The top ring appears from the pics to be symmetrical, so just put the marking up. The second ring is a Napier design so the groove goes down, which also happens to place the markings up as well.