Infineum- Investigating LSPI

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Originally Posted By: Solarent
Originally Posted By: Virtus_Probi
Hmmm...they didn't experiment with varying the magnesium levels?
Seems like M1 and Castrol keep a reasonable TBN by adding magnesium when they drop the calcium. Mobil 1 ESP just cuts the calcium, adds no magnesium, and lives with a lower TBN with the benefit of a SAPS lower than M1 (I think).


We really can't know exactly what the formulators did. Here on BITOG we compare VOA and PQIA data and assume we know what kinds of detergents/dispersants are being used. In reality - while a lot of things can be inferred by these kinds of reports oil formulas are much more complex than that.

One thing is certain - if it was as easy as substituting a magnesium detergent for a calcium one then everyone would have done it and there would be no need for developing a new LSPI test for the next category upgrade. There is still lots to learn and as TGDI engines take over the market over the next 5 years, I feel like there are still lots to learn that we probably haven't even thought about yet.


You are absolutely right...I saw that M1 and Castrol had lower calcium levels than other 5W30 synths with good TBNs and guessed that their higher magnesium levels explained that. It's just a basically uninformed guess, but I did peek at the periodic table to see that Ca and Mg are in the same column (which is an indicator that they might have similar chemical properties).
Should be put in the same category as my thoughts about Chinese airstrips in the South China Sea and the search for the Higgs boson, the rambling of a dilettante!
;^)
 
I do think it's a bit rich that Lexus are rah-rah'ing about developing a new calcium-free engine oil. In all probability this will be based on magnesium - the very same magnesium that Japanese industry virtually banned for years on the ridiculous basis that it caused bore glazing!

Personally I always liked Mg simply because it's a darn sight easier and cheaper to make a 400 TBN Mg detergent than it is with Ca. Also, it also gives you slightly less ash for a given TBN.
 
Originally Posted By: Virtus_Probi
You are absolutely right...I saw that M1 and Castrol had lower calcium levels than other 5W30 synths with good TBNs and guessed that their higher magnesium levels explained that. .


Castrol doesn't have much magnesium anymore. Ca: 1950 and Mg: 8 ppm

https://bobistheoilguy.com/forums/ubbthreads.php/topics/3654365/Re:_Castrol_Edge_Extended_Perf and
http://www.bobistheoilguy.com/forums/ubb...20_-_02_Chevy_S and
https://bobistheoilguy.com/forums/ubbthreads.php/topics/3745866/2013_Mini_Cooper_S_-_Castrol_E and
https://bobistheoilguy.com/forums/ubbthreads.php/topics/3839330/Castrol_Magnatec_5-30,_7100mil

Although Castrol Edge 0w-40 (euro) has the same amount of calcium WITH more magnesium than the dexos1-qualified Edges.
https://bobistheoilguy.com/forums/ubbthreads.php/topics/3840615/Castrol_Edge_Titanium_0W40_507
 
Castrol varies it's Calcium / Magnesium according to viscosity, and i'm sure for other 'proprietary' reasons as well.


EDGE black 5w30 (Low Calcium / High Magnesuim)
http://www.pqiamerica.com/March2013PCMO/castroledgesyn.htm

EDGE gold 0w20 (Low Calcium / High Magnesium)
http://www.pqiamerica.com/June 2014/castrol.htm

GTX 5w30 (Low Calcium / High Magnesium)
http://www.pqiamerica.com/CastrolGTX.htm

GTX 10w40 (High Calcium / Low Magnesium)
http://www.pqiadata.org/CastrolGTX10W40.html

GTX 5w20 (High Calcium / Low Magnesium)
http://www.pqiamerica.com/Nov2013/Castrol.htm
 
lubricatosaurus, not sure if you meant to use this one, but the link below is for Castrol 5W30 Turbo Diesel (not recommended for any T-GDI PCMO i know of). Probably not a bad choice though, just being critical.
smile.gif


https://bobistheoilguy.com/forums/ubbthreads.php/topics/3745866/2013_Mini_Cooper_S_-_Castrol_E

I don't know how we can say anything definitive one way or the other. These companies are always tinkering with their formulations.

And this one is from June 2014:
EDGE gold 0w20 (Low Calcium / High Magnesium)
http://www.pqiamerica.com/June 2014/castrol.htm
21.gif
 
Originally Posted By: lubricatosaurus
wemay, your 2013 references are too old, not true anymore. Castrol has gotten away from Mg in all oils.

All is a very big word. I bet they haven't in their HDEOs.
 
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