I've thought a few times about packing some "red rubber grease" into the piston, what with all the road salt we have here. You know, remove caliper, put in the tool so that the piston can't shoot out, get the piston out a ways. Pry back the boot. Pack some grease in there (the red rubber stuff is supposed to good for this, although I've come across some links of people using Sil-Glyde with no ill effects). Crack the bleeder then push the piston in. Will it make a difference? No idea, haven't done it yet. But I've lost a few calipers over the years from rust on the piston causing seizing.
I don't put brake grease onto the brake shims. I did it once and it squealed. Never again.
I make sure the slider pins are working fine. I picked up some Sil-Glyde recently to try out.
Once I know the pads are sliding properly (sometimes a file has to be used on the pad ears), I apply Honda M77 assembly moly (as per The_Critic) onto the pad ears. And onto the caliper bracket where the shims will sit, in an attempt to keep rust at bay. Assemble and call it done. Until next year--for me I find it best to bust it all apart every spring, else stuff tends to freeze up.
FWIW, there's a lot to be said for removing the caliper bracket as it makes it real easy to fully clean it. Once off, pop the rotor off and slap some anti-seize back there--that way when it needs to come off in the future, it will.
I find rear disc brakes need more attention than fronts. YMMV.