To answer your question on carbon buildup with 100% gas as compared to 10% ethanol gas regardless of octane...not that I am aware of!
However, there is a fuel economy benefit for 100% gasoline but, what is the delta on the paying higher prices for 100% gas as compared to just regular 87-93 octane. To me, it's all bottom line.
I have or had vehicles for 16, 18 & over 30 years and the same with lawnmower/snowblower, weedwacker/leafblower all without any fuel issues using just regular 87 octane fuel and over the past 25-30 years(that I am aware of), using 10% ethanol.
In most areas that I am aware of, 100% gas is only the highest octane gas at a filling station. All other lower octane gasoline is 10% ethanol gas. IDK where in the U.S. that there is more 100% gas compared to other regions of the U.S. I only know my area in which I live & buy fuel.
Also, some gasoline brands tout that they use the same detergent amount in all octanes of gas and others do not(the higher the octane, the more detergent).
I personally have not had any engine or fuel system failures by using just regular 87 octane w/ 10% ethanol. NOT in my vehicles, in which I have driven for decades & many 100K, 200K & 300K miles. NOR have I had any issues with my Outdoor Power Equipment(OPE).
Maybe my vehicles &/or OPE would/might run noticeably better with 100% gasoline but, I've never felt that they run poorly. Infact, everything that I own runs quite well, even perfect. They all start quickly, idle smoothly and rev freely on 10% ethanol 87 octane gas. And for the most part, meet the expected MPG!