The Peak should be fine. Peak seems to hold up longer than other coolants if kept in decent climate.
I had two jugs open that sat for about eight years. What I usually do is get a full strength gallon, and pour half into an empty gallon and fill the rest of the way up with distilled water; hence two 50/50 mixes for the price of one. As such, I always have an extra full jug put away in storage.
Well, I found these two gallons of 50/50 mix that I had forgotten about over the years. One was Peak, the other Prestone. The peak was still a deep hue of green, the Prestone had turned rather cloudy and milky. I threw the Prestone out and used the Peak. I know it's not a scientific process for determining the shelf life, but it shore were a pretty green!