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From the savantgroup PDF page 4 "In a further analysis of the IOM data, it was unexpectedly found that phosphorus volatility also unrelated to phosphorus concentration in fresh oil [19,20] as shown in figure 4." Very intresting reading Thanks for the links 427. I was unaware of this. In some of the documents a linkage is mentioned regarding the oils NOACK volatility and ZDDP(Phosphorus) contamination of the Cat. I stll maintain that a non oil burner will poison the Cat less. Rickey.
Well, you cherry picked the data from ONE study so I don't consider your conclusion worthy of much consideration.
Some points to consider.
First, the use of a modified Selby-Noack Volatility Test is a bench test that measures Phosphorus volatility of formulated oils when exposed to prescribed amount of heat and air for ONE hour. This is not identical to the decomposition of ZDDP in an operating engine (see Fig 6
http://www.practicingoilanalysis.com/article_detail.asp?articleid=477). The reason you still see Zinc in a used oil analysis is that much of the Zinc portion of ZDDP remains.
Second, while the survey conducted of oils showed no correlation between original ZDDP levels and the Selby-Noack Volatility Test PEI, they didn't conclude that if you doubled the levels of ZDDP for a particular formulation, you wouldn't double the PEI levels. In any case, as I already mentioned above, this is a ONE hour bench test.
Third, if Phosphorus poisoning of the Cat could be prevented with just a reformulation of the oil with a different form of ZDDP, don't you think the Lubrication and Automobile industries would of avoided all the time and effort they have to reduce ZDDP levels during the past 5 years? Most of that research in bibliography was conducted before GF-4/SM/CJ4 limits were considered, so if this paper has any validity, don't you think someone would of noticed?
Lastly, Savant has been known to be antagonist to ZDDP reduction. Could it be they have an ulterior motive? Possibly a lack of funds or will to find a ZDDP replacement? However, just like Fox news, I try to be fair and balanced and present all sides to inspire a deeper understanding of the topic at hand.