Originally Posted By: Injured_Again
User "wag123" wrote this in another thread:
For those of you who have not done this, our host has provided reading material on this website about what MoS2 does and how it works (including electron microscope images of how MoS2 bonds to the wear parts inside an engine). Also, note in your reading that our host endorses the use of Mos2.
http://www.bobistheoilguy.com/moly-basics/
http://www.bobistheoilguy.com/applications-for-lubrication/
http://www.bobistheoilguy.com/what-is-blow-by/
BITOG does not "endorse" using MoS2 - there are articles put up as FYIs and to help people learn.
I agree with demarpaint's assessment that the particles may well fill voids and reduce consumption, but they still are particles. And particles, even at 100nm, are HUGE compared to a molecular MoS2. Plus, DLVO and other forces will prevent them from staying that small.
None of this means that there is MoS2 CHEMICALLY ADSORBED onto the surface. Fine particles may sit on the surface, and they may break into finer particles under shear (though suspended particles often shear thicken) in the tight contact areas. But I am convinced the MoS2 on the surface is due to physical pressure forcing particles into a rough surface (think chalk on a concrete sidewalk), not any sort of chemical bonding.
The comment that ceratec will somehow attach to the surface once the MoS2 has worn away is just not consistent with the surface science of this stuff as I understand it. There is no competitive adsorption of any of this stuff chemically to the surface, because there isnt a practical atomic interaction, IMO (this is why we have other soluble molys in oils, not particulate MoS2 - because they have functional groups that will interact with the surface). Going back to the chalk on the sidewalk concept, think pebbles on the sidewalk. If you rub a pebble on the sidewalk, some will scuff off (fine dust), and the pebbles (big particles analog) will still sit there. Neither the dust nor the pebbles will be attached chemically to the sidewalk. Blow either off and its gone. Similarly, take a second pebble, different color and different kind of rock, and it too will mix in as a stripe on the sidewalk. The dust that comes off may be a different particle size or something, but it neither chemically displaces or chemically alters the concrete surface. If you rub pebble #2 on the stripe you drew with pebble #1, youll have a mix of both dusts in there (and anything displaced would be due to physical "pushing" of it). No chemical reaction = no formal displacement of what is affixed to the surface (because nothing is strongly affixed).
Thus what youll get from the first instant is a mix of the two materials, which may or may not be compatible, and the bigger particles will carry the load and the smaller ones will sit interstitially. One particle may be better than the other for some reason like ability to stabilize in solution, inertness, particle size, etc., but the bigger particle "fines" in the nooks and crannies will always be the first to provide boundary lubrication.
Again, its a nitpick, but as Ive defined it is more appropriate to the surface science as I understand it.