quote:
The ATF has approximately 12-18 different additives in the base fluid, which is generally a paraffinic mineral oil. Later base fluid developments introduced Polyalpha olefins (PAO’s), di-esters, POE esters, alkylated naphthalenes, and alkylated benzenes for better oxidation and thermal resistance.
Of those additives, Ant-Wear (AW) and Friction-Modifcation additives are the most important. Most frictional materials in automatic transmissions are steel making contact with a steel-backed plate containing a surface made of fiber such as cellulose. The cellulose frictional material is bound by resins and may contain other materials such as carbon, asbestos fibers, or ceramics. The frictional materials in future automatic transmissions will contain mostly carbon fiber composites and ceramics.
Each manufacturer uses different clutch materials so the dynamic friction of each transmission is slightly different, hence the requirement for fluids of different dynamic frictional [and static] characteristics.
For heavy duty truck transmissions, sintered bronze and semi-metallic friction surfaces are the norm (such as used in Allison Transmissions).
Friction Modification:
When we use the term, “Friction-Modification” with a hyphen “-“ we infer a special friction additive that affects the “Dynamic” friction coefficients under spinning wet-type clutch plates and drums.
Dynamic friction is defined as the “changing of the coefficient of friction as the sliding speed between two frictional surfaces change.”
The friction coefficient of Dexron III/Mercon fluid increases as the sliding speed increases. The friction coefficient of Ford Type F fluid decreases as the sliding speed increases.
Stating the above sentence another way, Ford Type F fluid has a Low Cf at high speeds, and a high Cf at low speeds. Conversely, Dexron Type fluids have a High Cf at high speeds and a Low Cf at low speeds.
Highly specialized Friction-Modification additives determine the dynamic frictional characteristics of ATF’s. The F-M’s must be stable over long periods of usage; i.e., they must not change their dynamic frictional characteristics for at least 30,000 miles. These F-M additives will not show up in VOA's or UOA's.
Also see:
http://www.baumannengineering.com/alphabet.htm
http://www.edmunds.com/ownership/techcenter/articles/43836/article.html