3. Condition Caused Contamination:
There is three MAJOR conditions caused contaminants that are formed within the lube oil during normal use: Oxidation, Nitration, and Acid. These contaminants are formed when solid and moisture contaminants are present, and certain operating conditions exist within the engine. Consequently, it is imperative that these contaminants be removed from the system as fast as possible.
a) Oxidation: Oxidation occurs when the hydrocarbon constituents (and other products) of lube oil chemically combine with oxygen. Engine oil will combine with available oxygen under certain conditions to form a wide variety of oxidation products. Many of these direct or primary oxidation products combine with other materials such as wear metals, solid contamination, and moisture, to form second and third derivative products. As with most chemical reactions, oil oxidation is accelerated by heat and pressure. Heat, in particular, will speed up the oxidation process. Various studies have shown that lube oxidation rates (with many variables such as the lubricant and additive package in the lubricant) can be doubled for every 15 to 20 degrees increase over 180 degrees F. Also, engine loads, which will influence the levels of oxygen and pressure within the engine, can accelerate acid formation, corrosion, oil thickening, deposit formation, and accelerated wear.
Solid contaminants tend to hold heat, thereby increasing the temperature of the oil around the solid contamination. Combine this effect with the presence of moisture (H2O) from normal condensation, and the oxidation process accelerates even faster. When moisture is present in the lubrication system, the level of oxygen available to mix with hydrocarbons in the lube oil is raised dramatically. The presence of normal solid and moisture contamination, combined with demanding operating loads of the equipment, will produce high oil oxidation rates, even with normal oil temperatures.
All top quality lube oils have an additive package that contains oxidation inhibitors to slow the oxidation process as well as alkaline detergents that will neutralize acids formed by oxidation. Normally these additives will only last a certain length of time before they are depleted and the oil must be drained.
There are very few bypass systems that can step to the plate to control all the contamination problems of the engines oil. Eliminating the contaminants reduces oxidation and preserves the additive pack.
Remember, some engines will use a certain, very limited amount of oil each operating day. This minor amount needs to be replaced. This limited quantity of new oil, combined with the "top off" oil added at the time the bypass filter is changed, will maintain a sufficient amount of active additives to keep oxidation in check indefinitely.
b) Nitration: The combustion chambers of engines provide one of the few environments where there is sufficient heat and pressure to break the atmospheric nitrogen molecule down to a point that it reacts with oxygen and forms nitrous oxides (NOx). When nitrogen oxide products enter the lube oil through normal blow-by, they react with any moisture present in the lube and become very acidic, rapidly accelerating the oxidation rate of the oil. Proper bypass filtration can control the effects of nitration in the same ways it controls oxidation. And again, using cleaner engine oil as a seal between the ring and liner, blow-by of NOx components can be kept to a minimum in the first place.