On the DI engines, particularly the ones without port injection incorporated, it is soot. The soot is from the combustion process and a good hard throttle application clears a lot of it out the exhaust. On the ecoboosts, it is why the nice chrome exhaust tips are often black, and why I have a sooty spot on my garage floor from the cold exhaust dripping on the concrete. Definitely not oil.
One of the big reasons many engines are going to dual direct and port injection is to reduce this phenomena. An instance of where the DI engines got ahead of the emissions standards...