why one wouldn't prefer to use 4 over 3 given the higher boiling point.
The same chemicals that give it the higher wet boiling point (borate esters) absorb moisture more readily. Changing it regularly is more important with DOT4 than with DOT3.
I was in the local NAPA franchise store a while back, picked up a bottle of the
synthetic DOT4 brake fluid and took it to the counter. The parts guy, an experienced clerk there who is very helpful, asked me if I was sure I wanted the synthetic version. I told him that it was all synthetic, and the label was just marketing hype. I'm not sure he believed me.