Ethanol is a polar solvent (electro-negative) but is capable of dissolving both polar and non-polar compounds as the core ethyl group (C2H5) is non-polar and thus attracts non-polar molecules. This matters when it comes to valve and chamber deposits, largely contributed by oil vapor, which are organic polar compounds. Gasoline is a mixture of aromatics, alkenes, alkanes, and cycloalkanes. The aromatics like toluene and xylene, containing a benzene ring, are non-polar solvents. The alkanes, like 224TMP, are also non-polar solvents. It's much the same for alkenes and cycloalkanes. You won't get much cleaning of polar compounds with ethanol-free gasoline. You will with E10 as the ethanol introduces a polar solvent.