It takes a lot to get alternator this hot. I had a test mule years ago with an alternator bolted to a small OPE engine. A regular alternator dumping full load can get too hot to touch, but I can’t see boiling water.
212+F? I suspect the diode pack is weak.
Note, field windings at full 12V can hear the machine a good bit as well. Eventually I think those alone can probably reach mid-100s. Folks do weld with automotive alts in bursts.
Also, I’m not sure I hold to the “weak batteries wear them out” belief, as even with a weak battery, they can’t absorb big amps for more than tens of seconds before the vehicle voltage gets too high due to internal battery resistance. This can be studied as simply as with an in-dash ammeter and voltmeter setup. We can wish weak batteries could pull down big current for faster charging, but in my observations they don’t. My old school chargers output higher than the typical 14ish vehicle volts to get big amp charges in there.