First of all, the tire pressures recommended by the manufacturer are cold tire pressures for the load range handled by the OEM tire. (Some models have multiple recommendations based upon the load carried by the vehicle.) Just remember that lower than recommended cold inflation values will increase tire rolling resistance resulting in lower MPG.
Second, checking your tire pressures cold at least once a week with the same tire pressure gauge isn't a bad idea. (You'll find a slow leaker quicker this way.)
Many things affect hot tire pressure, e.g., outside temperature, vehicle weight, sustained high speed (Interstate) driving, etc. For every 10F change in outside temperature, you tire can either gain or loss a pound of pressure. (Park all day with one side of the car facing the sun and the other side in shade, you'll find the side in the sun has the higher tires pressures.) Trying to adjust hot tire pressures rather than cold tire pressures is best left to those that race. They have reams of data that take into account air temp, track temp, track grip, tire grip, etc.
Personally, I run the recommended cold tire pressure all year round (except when autocrossing or during track days). My owner's manual gives me other recommended tire pressures for "softening" a harsh ride (lower cold pressures to allow the tire to absorb some of the bumps) or when enjoying "spirited" driving (higher cold pressures to stiffen the sidewalls to improve transient steering response).
YMMV as to what cold tire pressures work best for your vehicle; but be sure to watch your tire wear, and don't exceed the max inflation PSI stated on your tire's sidewall as a safety precaution.