I don't "refuse to understand" anything. That highlighted statement is simply not true.Yes there is lots of nitrogen in ambient air, so what? Using Nitrogen is all about eliminating the oxygen. Not quite sure why people refuse to understand that. It has less to do with more oxygen than it does Eliminating O2 down to a couple PSI. Eliminate to O2 and you eliminate the moisture content, and its the moisture content within the tire that contributes to the drastic changes in tire pressure. I choose the inert gas and get very little deviance in temp related pressure changes.
Basic chemistry - all gases, including 78% nitrogen - follow the universal gas law. Water vapor, at the temperatures and pressures at which car tires are operated, is included in that by the way. At high saturation, you can get some effects that vary from the ideal gas law. But we aren't talking about super high saturation, we are talking about filling with air - not water.
So, if you're looking for dry air - sure, use N2. But you can achieve the same effect by putting an inline drier on your compressor and changing the desiccant when it gets saturated..
Your N2 filled tire experiences precisely the same pressure changes that my 78% N2 tire experiences when exposed to the same changes in temperature. Nothing more "drastic" than that. The same. As it must be.
PV=nRT requires that N2 experiences the same change in pressure as dry air for the same change in temperature.
Further, N2 and O2 both carry moisture. You're not eliminating H2O by eliminating O2, I have no idea where that concept originated (N2 machine salesman, I suspect) but most N2 machines have a drier in the line.
Bottled N2 is sold dry. That's why we use bottled N2 on airplanes - it's dry. Both the dryness and the lack of oxygen (we don't want to support combustion when the tires are inside the airplane) are why airplanes use N2.
Airplane tires experience a large enough temperature change, from -65F to 250F in minutes, sometimes, seconds, that any moisture present can undergo a phase change, and that is what causes a big swing in pressures.
Your car is not experiencing temperature changes of that magnitude, but if you race, where you can get big temperature spikes, N2 might be worth it. Otherwise, dry air performs every bit as well, and with the same exact variation with respect to temperature as described by the equation above.