I once read a blurb about how hybrid batteries are built to expect a high number of smaller charges/discharges as it switches between gas/electricity.
PHEV’s often are made expecting more deep discharges as they typically are plugged in and turn into a normal hybrid after most of the battery is discharged (albeit, within normal operational bounds since there’s cushion programmed in there)
But even though I wrote all that out, it may, may not apply here and even if it did, I wouldn’t worry about it.
It’ll behave fine as a non-plug-in hybrid, the concern is that you’ll get slightly less economy than an identical hybrid with a smaller battery (less weight) and you may or may not have paid more for the bigger battery upfront. Not sure if the Volt is as appealing as a fuel saver when used primarily in hybrid mode though.
But I think you’ll be fine - worst case occasional mountain/charge mode use?
Anyways, you already bought the car so enjoy it!