quote:
Originally posted by Hirev:
Holy cow sounds like some people here are digging a grave for PAOs. Here a little something from some experts, to read on Group III vs Group IV.
Link Here
And Here
More Here
A bunch of Facts
Lot to read here. A few of my thoughts on it:
Fully agree the consistency of PAO is much better than the whole Group III, for the reasons given. That is the reason why one should be selective as to which Group III they use. That is what determines good Group III's from poor ones. GTL's will probably reach the ultimate for Group III's in this respect. It is also the reason why Group IV's have not improved as much lately.....less to do.
I thought the VI comment perhaps was a bit bias. The best III's equal or better PAO for native base oil VI. But again if you compare the average III, then probably true.
And then the interesting one on pour point depressant effect on VHVI III's. The graph has been posted here often as an example as to why PAO's are superior. Your link gave this dialogue, which exlains:
"The Scanning Brookfield chart on this page demonstrates the difference in viscometrics between a Synfluid® PAO and a pour point depressed mineral oil. A Group III mineral oil with a 0.1% PPD achieves an improved pour point, but to the detriment of the low-temperature viscometrics. You would expect the viscosity to improve with a lower pour point, but the opposite is true. As a result, the jump in the viscosity adversely effects the ability to pump at low temperatures. Some specifications have a low temperature MRV requirement. You see, "the jump hurts the pump."
However, I think that does not necessarily mean that Group III's are bad. What it really means is that if you are selecting one, don't do it based on pour point. Select a Group III that has good CCS and MRV viscosity, which is the real measure - as your posted article points out. And if you look at the specs you will find some of the Group III's are excellent and outperform PAO's, even though their Pour Point is signficantly poorer. And for a negative example look at the Quaker State full synthetic which rivals PAO's in pour point, but has miserable CCS and MRV. Your article is a good explaination as to why.
So all in all good articles but one needs to read closely to determine what they really mean. If anyone is digging a grave for PAO's I would suggest the biggest enemy is just production cost. GTL's from areas where gas production is restricted (flared), are going to make those products pretty attractive, as I believe Bruce pointed out.