Group III Synthetics better than Group IV?

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quote:

Originally posted by BlazerLT:

quote:

Originally posted by Ron AKA:

Red Line 5w20 - 3.3
Red Line 5w30 - 3.8
Mobil 1 5w20 - 2.6
Mobil 1 5w30 - 3.1

I would expect a 5w30 Mobil 1 to even outperform a 5w20 Redline on HP and mileage.

You REALLY to stop with your opinionated ASSUMPTIONS based off of white paper data. You are making yourself foolish with statements like this.


These are not opinionated assumptions. They are based on solid theory and research, that eventually lead to the GF-4/SM standards.

It is those that think Redline can defy simple physics by using unknown mysterious additives (that nobody else knows about!), that are making foolish assumptions.
 
quote:

Originally posted by Ron AKA:

quote:

Originally posted by BlazerLT:

quote:

Originally posted by Ron AKA:

Red Line 5w20 - 3.3
Red Line 5w30 - 3.8
Mobil 1 5w20 - 2.6
Mobil 1 5w30 - 3.1

I would expect a 5w30 Mobil 1 to even outperform a 5w20 Redline on HP and mileage.

You REALLY to stop with your opinionated ASSUMPTIONS based off of white paper data. You are making yourself foolish with statements like this.


These are not opinionated assumptions. They are based on solid theory and research, that eventually lead to the GF-4/SM standards.

It is those that think Redline can defy simple physics by using unknown mysterious additives (that nobody else knows about!), that are making foolish assumptions.


WOW!!

What theories? What solid reearch?

You have nothing and YOU ALONE are the one making all these assumptions up.

Seriously, give up, you are losing your fingernails as you try to grasp and hold on while slipping down the cliff of your factless and pointless assumption, factless theories and overall regurgitation of white paper data.
 
""It is not the PP drop off that I would be concerned about, just the CCS/MRV. Here is the table of values to compare.""

You mis my point as PCMO breakdown the PP/CCS/MRV ALL will suffer BUT a PAO based oil will not lose the cold end much or as fast as a GPIII.

And also you keep saying.

""PAO's are not nearly as good as their pour point would suggest"" Yes they are.
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""especially after the PAO's are blended to real viscosity and additives put in.""

First how do know the percent PAO or GPIII if any? in the oils you are looking at? to make a blanket statment like that and also if PAO is "affected" so is a GPIII.

Also remember some companies data sheets "quote" on MRV or CCS that they are MAX or less than whatever the MAX is and do not show actual data just that they meet the spec.
bruce
 
Originally posted by bruce381:
""It is not the PP drop off that I would be concerned about, just the CCS/MRV.""

You mis my point as PCMO breakdown the PP/CCS/MRV ALL will suffer BUT a PAO based oil will not lose the cold end much or as fast as a GPIII.

R - Actually my point was the PPD loss may not be as significant as it appears, as it is not what improves the CCS/MRV.

""PAO's are not nearly as good as their pour point would suggest"" Yes they are.

R - So why do they have great pour points and average CCS/MRV's, aside from your theory that Group III's immediately lose these properties?

""especially after the PAO's are blended to real viscosity and additives put in.""

First how do know the percent PAO or GPIII if any? in the oils you are looking at? to make a blanket statment like that and also if PAO is "affected" so is a GPIII.

R - You misunderstand. I'm suggesting that pour points suffer when the PAO viscosity is increased to the values required by the SAE grade (not really suggesting how they do it). And further the cold oil properties are degraded by other additives. So yes, if these additives degrade then PAO's may actually improve with respect to PP, as they age. However, some may worry that thinning out of the oil from the grade that they thought they bought is not necessarily a good thing.

"Also remember some companies data sheets "quote" on MRV or CCS that they are MAX or less than whatever the MAX is and do not show actual data just that they meet the spec.
bruce"

R - I appreciate that, and I would suggest that it their problem, as it is them that is selling and I am buying. I do however look at what the standard is, and what they are quoting. If they are the same then of course the data is meaningless. They are just telling me that they are not committing fraud. If they are within the standard but considered a product max limit, then again that is their problem, that they don't want to show typical. If their max is quite high compared to typical then they must have a quality control problem.

Again just my thoughts, on an obviously controversial subject. I've bought Mobil 1 for many years, but if another product comes along that is the same for less $$, or better for the same $$ then it gets my attention.
 
quote:

Originally posted by Ron AKA:

quote:

Originally posted by BlazerLT:
......bla, bla,

I remember now. You are the one that never posts anything worth a response.


But...at least my posts have substance, which is not exactly what your posts about group 3 oil and petro-Canada have.
 
quote:

Originally posted by Ron AKA:

quote:

Originally posted by 427Z06:
It was I who first enlightened you to the relationship between PPDs and viscosity with Group IIIs, so you don't have to repeat this fact back to me.

Actually I recall it was you that posted that misleading graph of PAO viscosity vs temp compared to a GIII with PPD.


I mislead you? The only mistake I made was assuming you had enough knowledge and smarts to understand what was being presented.

I showed you this graph, in this post, to help explain to you the advantage PAOs had over group III basestocks at extreme low temps.

quote:

Originally posted by Ron AKA:
When another contributer posted the complete link which had the explanation of the graph and this was combined with specifications of final product pour points and CCS/MRV, then there actually was some learning. i.e. PAO's are not nearly as good as their pour point would suggest - especially after the PAO's are blended to real viscosity and additives put in.

Here's the explaination you allude to. If I would of known how hard it is for you to comprehend the simplest of concepts, maybe I would of posted a link to the explanation as well. But the point looks moot now. No matter how many people try to point out your errors you just ignore them, kept posting false assumptions and/or conclusions, or start another thread.

quote:

Originally posted by Ron AKA:
I have not seen a split between CCS/MRV - when one is good, the other usually is. The split comes in between PP and CCS/MRV, with the conclusion that PP especially of the base oil is meaningless.

Because you keep on looking at final products where the Group III formulations are already doped with PPDs. Ask yourself this, why aren't MRV specs posted along with the other viscometrics on the Group III spec sheets?

By the way, did you take my advice and look up the difference between CCS and MRV yet? Do you understand the difference?

Ron, you continue to demonstrate a complete lack of ability to synthesize all the knowledge presented by dozens of people here. Heck, Bruce who formulates oils for a living can't seem to get through to you. So I have to ask, have you suffered a stroke or concussion or something? I have a hard time believing anyone with an engineering degree could be so slow integrating all the information presented to them, and yet still end up with the wrong answers.
 
Hey, man, backoff! Even a learned dude is allowed to have (cue dramatic music) EPISODES
shocked.gif
(visions of Bender in The Breakfast Club, "Show **** some respect!!")

He never said that he was an emotionally/mentally stable engineer
dunno.gif


Now if you start hearing about "universal cross viscosity oils" that meet military spec's ..then a little voice should start whispering in your ear (visions of Airplane, "That's funny, John never vomits at home")
 
quote:

Originally posted by Gary Allan:
Hey, man, backoff! Even a learned dude is allowed to have (cue dramatic music) EPISODES
shocked.gif
(visions of Bender in The Breakfast Club, "Show **** some respect!!")


Oh, OK. Mongo only pawn in game of life.
lol.gif
 
Ron is playing the role of Andy Kaufman, or the "bad guy" on Saturday Morning wrestling. He is using the bitog memebers focused pursuit of "oil truth" against them by vacillating from an arrogant,authoritarian tone of voice to patronizingly inquistive remarks. He is simply quite adept at pushing buttons. The topic itself is interesting without feeding into him personally....although ironically and hypocritically I just did this. I did not say he was acting like a borderline personality either.
 
Hmmm...now that we have a Psychologist on board here. Let me ask you, could it be that Ron is one of those S&M/B&D types? Performing what's called, "topping from the bottom" maneuvers?
wink.gif
 
427ZO6,

Ron reminds me of Nicholson in a Few Good Men:

"You want the truth? You can't handle the truth!" LOL!


This thread deserves a mercy killing...where's Doctor K when you need him?


TS
 
I went back and re-read Bruce's comments. He doesn't seem to contradict Ron. He actually seems to agree on the main issue, GrpIII almost as good as GrpIV.

Ron,
The scientific method requires not only a single experiment producing certain values, but multiple experiments by multiple people and different places being able to reliably produce the exact same results. Therefore, it is not valid to collect a few numbers for few oils, compare them and then make all sorts of broad conclusions. I think what Blazer & Co are trying to say is that you need much more info/data for bigger/broader conclusions.

If I understood Bruce, IIIs need much more additives than IVs. Hence chances are much higher that the additives will be "spent" over time thus depriving IIIs from their effects.

Ron, assuming 100% correct data ion spec sheets from companies, the comparison is not important at T0 (when you put brand new oil into motor) but instead performance at T1, T2,... (1-2-3 months hence). How fast are additives spent in IIIs and IVs and how oil characteristics change, etc. Clearly there are no spec sheets for T1,T2,...

Lacking such data, we (amateurs) cannot do much but guess and extrapolate, so much so that end conclusions are likely to be way off. No point. The few professionals who work in the industry likely have access to much more data, as well as much better unerstanding of the chemistries, etc. So they are much better equiped to make conclusions, etc.

Since the issue of additives and their loss has been brought up, I have a couple of questions. First and foremost, what exactly is the rate of loss of additives? Sorry, I know, very broad question, engine type, additive type, etc. I am just trying to get a feel for it. Are they mostly spend after 2-3 months, or 6 months or ...? For instance, if you have an average commute to work car (say 2ishL, I4) and do mundane 50/50 city/highway commute to work. Then if I used one of these new GrpIIIs for a mundane 6month/5K OCI, will additives will be shot to ****? Mostly spent or half gone or ....? Again, just a feel.

If these additives in IIIs can hold up for a non-long OCI and GrpIII oil can maintain comparable characteristics to GrpIVs, in particular CCS/MRV for the coming winter, then the original premise that IIIs can be as good as IVs seems to be more or less correct, no? Not sure if I'd go as far as to say IIIs are better?

Anyway I am just wondering about additives and how robust they are. As far as pricing, while many people complain about Castrol Syntec being as expensive as M1, at least in Canada I believe we have other GrpIIIs that are much cheaper. And for those of use who have small sumps (small I4 Hondas, Mazdas, etc) the long OCI is not a good idea anyway.
 
quote:

Originally posted by Ron AKA:
If you read that paper by the Shell engineer, you will see that what they found was that engine friction losses were most strongly correlated to HT/HS viscosity, not just SAE grades.

You focus so much on this one "fact". If you took a college sceince class hopefully they taught you that correlation does NOT equal causation.

 -
 
Ron stop with the GPIII is better correct data on a 6 cSt PAO I use.
CP Chem...............Pet Canada VHVI
Vis 5.8...............6.0
PP -78F...............5F
Flash 460F............446F
VI 130................127
NOACK 6.5.............???? most likely 8-10?

My comment on "data" sheets is they MAY NOT be accurate and only ballpark so do not put a lot of stock to that that includes all the RL and other HTHS data.

Lets leave this and say anything GPIII can do a PAO can do the same but with lower NOACK and PP,CCS,MRV clod point and any other point.
bruce
 
quote:

Originally posted by bob_ninja:
Since the issue of additives and their loss has been brought up, I have a couple of questions. First and foremost, what exactly is the rate of loss of additives? Sorry, I know, very broad question, engine type, additive type, etc. I am just trying to get a feel for it. Are they mostly spend after 2-3 months, or 6 months or ...? For instance, if you have an average commute to work car (say 2ishL, I4) and do mundane 50/50 city/highway commute to work. Then if I used one of these new GrpIIIs for a mundane 6month/5K OCI, will additives will be shot to ****? Mostly spent or half gone or ....? Again, just a feel.

One indicator that might useful is the Sequence IIIGA Test for SM/GF-4 certification. The oil used in the Sequence IIIG test is measured for cold temp properties.

http://www.swri.org/4org/d08/GasTests/iiiga.pdf
 
""R - Actually my point was the PPD loss may not be as significant as it appears, as it is not what improves the CCS/MRV.""

Wrong PP,CCS,MRV drop off are real and happen in use a PAO will not have near the drop off if at all believe it or not.

""R - So why do they have great pour points and average CCS/MRV's, aside from your theory that Group III's immediately lose these properties?""

What theory it is a proven fact.
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And I did not say immediately.

Average compared to what GPIII need a PPD or they will not work find a unadditized CCS on a GPIII it will be higher than a PAO.

""R - You misunderstand. I'm suggesting that pour points suffer when the PAO viscosity is increased to the values required by the SAE grade (not really suggesting how they do it).""

Wrong not true in all cases is oil system dependant.

""And further the cold oil properties are degraded by other additives.""

Wrong again see above

Bruce
 
quote:

Lets leave this and say anything GPIII can do a PAO can do the same but with lower NOACK and PP,CCS,MRV clod point and any other point.
bruce

cheers.gif


Ron, bruce is a formulator and knows more than any of us so just drop it. You're arguing with the wrong person.
 
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